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网站主页CAS数据库列表 348-51-6更多图谱2-氯氟苯(348-51-6)Raman光谱

2-氯氟苯

产品名称 2-氯氟苯

CAS号348-51-6

分子式C6H4ClF

分子量130.55

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  • Mass

    MS-NW-1003          
    o-chlorofluorobenzene
    C6H4ClF             (Mass of molecular ion:    130)
    

       Source Temperature: 260 °C
       Sample Temperature: 130 °C
       Reservoir, 75 eV
    

          28.0       1.1
          31.0       1.2
          37.0       1.7
          38.0       1.1
          39.0       1.0
          49.0       1.1
          50.0       5.2
          51.0       2.1
          61.0       1.3
          62.0       1.2
          63.0       1.7
          65.0       2.7
          68.0       3.6
          69.0       3.8
          70.0       1.1
          73.0       1.3
          74.0       3.8
          75.0      13.4
          76.0       1.1
          93.0       2.3
          94.0       6.2
          95.0      39.6
          96.0       2.6
         104.0       1.3
         130.0     100.0
         131.0       6.8
         132.0      31.9
         133.0       2.1
    

parameter in CCl4

90 MHz in CDCl3

400 MHz in CDCl3


  • 1H NMR 300 MHz
    C6 H4 Cl F 10 vol% in CCl4
    o-chlorofluorobenzene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.34 D(B) 7.01 D(C) 7.16 D(D) 7.07 D(X) -1.18 J(A,B) 8.01 J(A,C) 1.70 J(A,D) 0.31 J(A,X) 7.33 J(B,C) 7.47 J(B,D) 1.46 J(B,X) -0.87 J(C,D) 8.29 J(C,X) 4.79 J(D,X) 9.10 ROARK,J.L. & SMITH,W.B. J.PHYS.CHEM. 73, 1046 (1969) F-19 REFERENCE : 1,1,2,2-TETRACHLORO-3,3,4,4-TETRAFLUOROCYCLOBUTANE

         Hz     ppm     Int.
    

       2210.63   7.369    491
       2208.97   7.363    520
       2202.95   7.343   1000
       2201.35   7.338    948
       2195.20   7.317    591
       2193.59   7.312    675
       2159.97   7.200    209
       2158.26   7.194    205
       2154.84   7.183    273
       2152.81   7.176    429
       2151.67   7.172    466
       2151.07   7.170    376
       2149.98   7.167    414
       2146.99   7.157    463
       2145.42   7.151    538
       2144.45   7.148    608
       2142.73   7.142    519
       2139.41   7.131    538
       2137.85   7.126    496
       2129.84   7.099    640
       2128.24   7.094    808
       2120.81   7.069    851
       2118.89   7.063    826
       2112.93   7.043    490
       2111.89   7.040    478
       2110.63   7.035    888
       2108.87   7.030    452
       2104.47   7.015    485
       2103.87   7.013    558
       2103.26   7.011    591
       2102.44   7.008    867
       2100.98   7.003    471
       2096.54   6.988    365
       2095.33   6.984    344
       2094.47   6.982    326
       2093.69   6.979    302
    


  • 1H NMR 89.56 MHz
    C6 H4 Cl F 0.02 ml : 0.5 ml CDCl3
    o-chlorofluorobenzene
    ChemicalStructure
        Assign.     Shift(ppm)
    A 6.96 to 7.49

         Hz     ppm     Int.
    

        668.81   7.468    191
        667.94   7.459    186
        663.25   7.406    221
        662.31   7.396    197
        661.50   7.387    338
        660.63   7.377    356
        655.81   7.323    179
        653.56   7.298    393
        651.81   7.278    187
        649.94   7.258    256
        648.88   7.246    166
        647.50   7.230    172
        646.81   7.223    212
        646.06   7.214    349
        645.63   7.209    533
        644.69   7.199    273
        643.88   7.190    926
        643.06   7.181    470
        640.75   7.155    558
        639.69   7.143    490
        638.31   7.128   1000
        637.56   7.119    316
        636.69   7.110    677
        634.94   7.090    459
        633.69   7.076    359
        632.38   7.061    440
        630.56   7.041    166
        629.81   7.033    170
        629.25   7.027    292
        626.13   6.992    173
    


  • 1H NMR 399.65 MHz
    C6 H4 Cl F 0.05 ml : 0.5 ml CDCl3
    o-chlorofluorobenzene
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.361 B 7.198 C 7.102 D 7.050 J(A,B)=1.7HZ J(A,C)=0.4HZ J(A,D)=8.1HZ J(A,F-19)=7.4HZ J(B,C)=8.3HZ J(B,D)=7.4HZ J(B,F-19)=4.9HZ J(C,D)=1.6HZ J(C,F-19)=9.3HZ J(D,F-19)=0.7HZ

         Hz     ppm     Int.
    

       2955.81   7.396     36
       2954.83   7.394     36
       2950.81   7.384    623
       2950.44   7.383    630
       2949.10   7.380    708
       2948.73   7.379    603
       2943.36   7.365    789
       2942.75   7.364    910
       2941.65   7.361    873
       2941.16   7.360    907
       2935.42   7.345    701
       2935.06   7.345    692
       2933.72   7.341    742
       2933.35   7.340    716
       2929.20   7.330     36
       2893.19   7.240     41
       2891.97   7.237     30
       2889.04   7.229    370
       2887.45   7.225    381
       2884.28   7.218    391
       2882.57   7.213    448
       2881.71   7.211    582
       2880.74   7.209    590
       2880.00   7.207    564
       2879.15   7.205    624
       2876.83   7.199    563
       2875.85   7.196    605
       2875.12   7.195    581
       2874.27   7.192    640
       2873.41   7.190    803
       2871.70   7.186    705
       2868.53   7.178    737
       2866.82   7.174    679
       2863.04   7.164     32
       2862.55   7.163     30
       2861.57   7.161     31
       2858.03   7.152     31
       2851.44   7.135     41
       2847.53   7.126    766
       2845.95   7.122    901
       2843.14   7.115     89
       2842.65   7.113     91
       2842.16   7.112     92
       2841.67   7.111     94
       2838.99   7.104    677
       2838.38   7.103    792
       2838.01   7.102    915
       2837.65   7.101    788
       2836.79   7.099    987
       2836.43   7.098    935
       2834.11   7.092     99
       2829.71   7.081    604
       2828.49   7.078    599
       2828.13   7.077    600
       2826.05   7.072    741
       2825.20   7.070    729
       2824.46   7.068    655
       2823.73   7.066    619
       2820.92   7.059     91
       2818.60   7.053    720
       2817.99   7.052   1000
       2817.26   7.050    953
       2816.41   7.048    886
       2815.67   7.046    683
       2812.87   7.039     80
       2812.26   7.037     79
       2810.67   7.033    551
       2809.94   7.032    522
       2809.08   7.029    517
       2808.35   7.028    475
       2805.42   7.020     41
       2804.81   7.019     41
       2804.08   7.017     34
       2803.34   7.015     30
    

in CDCl3



liquid film



4880 A,100M,liquid