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网站主页CAS数据库列表 2531-84-2更多图谱2-甲基菲(2531-84-2)核磁图(1HNMR)

2-甲基菲

产品名称 2-甲基菲

CAS号2531-84-2

分子式C15H12

分子量192.26

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  • Mass

    MS-NW-0109          
    2-methylphenanthrene
    C15H12              (Mass of molecular ion:    192)
    

       Source Temperature: 130 °C
       Sample Temperature:   0 °C
       Direct, 75 eV
    

          39.0       1.3
          51.0       1.1
          62.0       1.0
          63.0       2.3
          69.0       1.0
          69.5       1.2
          74.0       1.5
          75.0       1.5
          81.5       1.6
          82.0       1.3
          82.5       3.5
          83.0       1.0
          86.0       1.0
          87.0       1.5
          93.5       1.1
          94.0       1.3
          94.5       4.3
          95.0       2.5
          95.5       1.1
          96.0       3.7
         115.0       1.1
         139.0       2.0
         150.0       1.7
         151.0       1.4
         152.0       1.9
         163.0       3.7
         164.0       2.1
         165.0      10.9
         166.0       1.7
         176.0       2.7
         187.0       2.6
         188.0       2.1
         189.0      19.5
         190.0      10.1
         191.0      36.5
         192.0     100.0
         193.0      16.4
         194.0       1.3
    

400 MHz in CDCl3

parameter in CCl4


  • 1H NMR 399.65 MHz
    C15 H12 0.9 mg : 0.5 ml CDCl3
    2-methylphenanthrene
    ChemicalStructure
        Assign.     Shift(ppm)
    A 8.656 B 8.583 C 7.875 D *1 7.713 E 7.68 F *1 7.682 G 7.638 J 7.571 K 7.491 L 2.568

         Hz     ppm     Int.
    

       3464.60   8.670     90
       3463.99   8.668    116
       3463.38   8.667    114
       3456.30   8.649     92
       3455.81   8.648    126
       3455.08   8.646    123
       3454.59   8.645     88
       3434.57   8.594    145
       3426.15   8.573    152
       3151.86   7.887    113
       3150.39   7.883    101
       3144.04   7.867    131
       3142.58   7.864    119
       3089.23   7.730     93
       3082.40   7.713     31
       3080.44   7.708    282
       3072.14   7.688    306
       3070.19   7.683    162
       3069.21   7.680    176
       3068.73   7.679    165
       3063.23   7.665     96
       3061.40   7.661     79
       3059.94   7.657     85
       3054.44   7.643    128
       3052.98   7.640    162
       3051.64   7.636     78
       3046.14   7.623    129
       3044.68   7.619    114
       3032.71   7.589    146
       3031.37   7.586    153
       3025.63   7.571    100
       3024.78   7.569    151
       3023.56   7.566    132
       3017.82   7.552     84
       3016.60   7.549     74
       2999.02   7.505    104
       2998.66   7.504     99
       2997.92   7.502     68
       2997.19   7.500     93
       2996.83   7.499     93
       2990.72   7.484     99
       2990.23   7.483    100
       2989.50   7.481     65
       2988.77   7.479     94
       1026.49   2.569   1000
    


  • 1H NMR 300 MHz
    C15 H12 in CCl4
    2-methylphenanthrene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.57 D(B) 7.36 D(C) 8.47 J(A,B) 1.8 J(A,C) 0.4 J(B,C) 8.7 D(D) 8.55 D(E) 7.525 D(F) 7.46 D(G) 7.755 J(D,E) 8.7 J(D,F) 1.15 J(D,G) 0.5 J(E,F) 6.9 J(E,G) 2.0 J(F,G) 7.7 D(J) 7.57 D(K) 7.57 D(L) 2.545 BARTLE,K.D. & SMITH,J.A.S. SPECTROCHIM.ACTA 23A, 1689 (1967) H(J) & H(K):BROADENED SINGLET.

         Hz     ppm     Int.
    

       2569.87   8.566     64
       2568.70   8.562     71
       2561.77   8.539     60
       2561.26   8.538     65
       2560.37   8.535     69
       2545.44   8.485    129
       2536.72   8.456    136
       2331.37   7.771     55
       2329.64   7.765     54
       2329.13   7.764     53
       2324.05   7.747     76
       2322.03   7.740     69
       2270.99   7.570    723
       2266.85   7.556     39
       2264.73   7.549     37
       2259.92   7.533     64
       2257.79   7.526     61
       2256.17   7.521     32
       2251.53   7.505     65
       2249.30   7.498     56
       2245.10   7.484     66
       2243.71   7.479     71
       2237.61   7.459     65
       2236.33   7.454     66
       2230.68   7.436     31
       2229.39   7.431     28
       2213.18   7.377     92
       2211.45   7.371     87
       2204.46   7.348     87
       2202.73   7.342     83
        763.48   2.545   1000
    

in CDCl3



KBr disc



4880 A,200 M,powder