-
MassMS-NW-4672 6-methyl-2-pyridylamine C6H8N2 (Mass of molecular ion: 108)
Source Temperature: 250 °C Sample Temperature: 180 °C Reservoir, 75 eV
15.0 1.3 18.0 2.3 26.0 1.0 27.0 2.8 28.0 5.1 37.0 2.4 38.0 5.4 39.0 17.4 40.0 4.5 41.0 9.6 42.0 8.2 43.0 2.3 50.0 1.6 51.0 2.7 52.0 3.9 53.0 6.8 54.0 4.0 62.0 1.1 63.0 2.5 64.0 5.0 65.0 5.5 66.0 12.1 67.0 2.6 68.0 3.2 79.0 1.1 80.0 51.7 81.0 39.7 82.0 2.7 91.0 9.5 92.0 2.3 93.0 4.1 107.0 3.4 108.0 100.0 109.0 7.4
parameter in CDCl3
90 MHz in CDCl3
-
1H NMR 300 MHz C6 H8 N2 20 % in CDCl3 2-amino-6-methylpyridine 
Parameter ppm Hz
D(A) 6.13 D(B) 7.14 D(C) 6.32 J(A,B) 8.1 J(A,C) 1.2 J(B,C) 7.3 D(D) 5.23 D(E) 2.28 BELL,C.L. ET AL. J.HETEROCYCL.CHEM. 2, 420 (1965)
Hz ppm Int.2149.82 7.166 79 2142.50 7.142 101 2141.77 7.139 100 2134.45 7.115 89 1900.22 6.334 92 1899.04 6.330 96 1892.89 6.310 88 1891.76 6.306 90 1843.59 6.145 95 1842.42 6.141 92 1835.50 6.118 90 1834.32 6.114 87 1569.02 5.230 667 684.02 2.280 1000
-
1H NMR 89.56 MHz C6 H8 N2 0.045 g : 0.5 ml CDCl3 6-methyl-2-pyridylamine Assign. Shift(ppm)
A 7.288 B 6.477 C 6.282 D 4.6 E 2.357
Hz ppm Int.660.94 7.380 102 653.56 7.298 151 653.00 7.292 137 645.44 7.207 142 583.38 6.514 147 582.88 6.509 119 576.00 6.432 118 575.50 6.426 95 566.25 6.323 142 565.69 6.317 111 558.94 6.241 85 558.19 6.233 120 557.56 6.226 91 411.75 4.598 38 211.13 2.358 1000
in CDCl3
CCl4 solution
KBr disc
liquid film
nujol mull
更多供应商
