2-降坎烷乙酸

Mass

MS-NW-5583          
2-norbornaneacetic acid
C9H14O2             (Mass of molecular ion:    154)

   Source Temperature: 270 °C
   Sample Temperature: 190 °C
   Reservoir, 75 eV

      15.0       1.1
      18.0       2.2
      26.0       1.4
      27.0      15.6
      28.0       4.2
      29.0       8.9
      31.0       1.2
      38.0       1.6
      39.0      24.8
      40.0       6.1
      41.0      34.7
      42.0       3.6
      43.0      11.2
      44.0       1.1
      45.0       5.4
      50.0       1.7
      51.0       4.4
      52.0       2.7
      53.0      13.6
      54.0      20.0
      55.0      19.1
      56.0       2.4
      57.0       3.4
      58.0       1.1
      60.0       7.4
      61.0       1.7
      63.0       1.3
      65.0       6.4
      66.0      29.7
      67.0     100.0
      68.0      52.5
      69.0       6.8
      70.0       4.8
      71.0      13.1
      72.0       1.5
      73.0       2.0
      77.0       8.5
      78.0       2.8
      79.0      34.7
      80.0      12.6
      81.0      11.9
      82.0       6.8
      83.0       5.9
      84.0       4.0
      85.0      46.9
      86.0       5.6
      87.0      20.5
      88.0       1.4
      91.0       5.1
      92.0       6.9
      93.0      10.0
      94.0      87.7
      95.0      62.7
      96.0       5.0
      97.0       3.1
      99.0       1.0
     100.0       1.3
     107.0       3.8
     108.0      16.4
     109.0       6.5
     111.0       1.7
     112.0       5.1
     113.0       3.8
     118.0       1.0
     121.0       1.8
     124.0       1.0
     125.0      10.8
     126.0       7.3
     136.0      19.8
     137.0       2.8
     139.0       1.5
     154.0       6.3

Assign. Shift(ppm) A 11.5 B *1 2.311 C 2.223 D *1 2.176 E *2 2.020 F 1.895 G *2 1.53 to 1.48 J *3 1.302 K 1.23 L 1.14 M *3 1.12 N 1.08 ASSIGNED BY C-H COSY

     Hz     ppm     Int.

    937.26   2.346    570
    929.39   2.326    614
    921.88   2.307    899
    914.00   2.288   1000
    888.72   2.224    627
    879.75   2.202    862
    872.06   2.183    921
    864.36   2.163    496
    856.67   2.144    578
    808.86   2.024    670
    806.30   2.018    619
    763.80   1.912    302
    758.86   1.899    326
    756.11   1.892    311
    751.17   1.880    296
    624.96   1.564    395
    622.77   1.559    345
    620.57   1.553    222
    616.54   1.543    364
    612.33   1.533    589
    610.31   1.528    494
    608.11   1.522    453
    604.27   1.512    575
    601.52   1.506    876
    597.67   1.496    783
    590.90   1.479    328
    589.61   1.476    277
    588.15   1.472    272
    586.87   1.469    349
    527.70   1.321    308
    526.05   1.317    439
    524.22   1.312    344
    517.81   1.296    406
    515.98   1.292    565
    514.33   1.287    437
    501.33   1.255    243
    491.62   1.231    442
    483.93   1.211    342
    481.73   1.206    311
    466.16   1.167    388
    464.33   1.162    342
    458.65   1.148    430
    456.82   1.144    548
    454.80   1.138    651
    453.34   1.135    635
    452.42   1.133    599
    450.96   1.129    525
    447.66   1.121    256
    446.19   1.117    331
    444.73   1.113    486
    443.45   1.110    560
    442.35   1.107    595
    439.42   1.100    371
    437.40   1.095    364
    434.65   1.088    370
    433.19   1.084    265
    429.89   1.076    306
    426.59   1.068    237
    424.95   1.064    302
    422.38   1.057    313
    420.73   1.053    219