1,6-ANHYDRO-3,4-O-ISOPROPYLIDENE-2-TOSYL-B-D-GALACTOPYRANOSE

Mass

MS-IW-0798          
1,6-anhydro-3,4-O-isopropylidene-2-o-tosyl-beta-D-galactopyranose
C16H20O7S           (Mass of molecular ion:    356)

   Source Temperature: 160 °C
   Sample Temperature: 140 °C
   Direct, 75 eV

      15.0       1.2
      18.0       3.8
      27.0       1.9
      28.0       1.6
      29.0       3.1
      31.0       4.2
      39.0       3.2
      41.0      10.7
      42.0       1.0
      43.0      20.5
      44.0       1.5
      45.0       2.3
      53.0       1.0
      55.0      25.0
      56.0       1.1
      57.0      23.3
      58.0       1.5
      59.0      18.7
      60.0       1.1
      65.0       6.1
      68.0       1.5
      69.0      56.9
      70.0       3.6
      71.0       7.2
      73.0       2.3
      81.0       7.2
      83.0       2.4
      85.0      11.3
      87.0       2.2
      89.0       1.4
      90.0       1.3
      91.0      29.4
      92.0       3.2
      97.0      17.1
      98.0       2.2
      99.0       1.5
     100.0       1.6
     101.0       4.7
     107.0       1.4
     108.0       1.9
     109.0       6.6
     113.0       1.3
     115.0       3.1
     126.0       1.0
     127.0       3.8
     139.0       4.4
     143.0     100.0
     144.0       7.0
     145.0       1.1
     155.0      28.0
     156.0       2.5
     157.0       1.5
     184.0       3.7
     185.0       1.9
     201.0      85.9
     202.0       8.8
     203.0       1.3
     341.0      15.4
     342.0       2.7
     343.0       1.1

Assign. Shift(ppm) A 7.835 B 7.373 C 5.247 D 4.498 E 4.479 F 4.388 G 4.123 J *1 4.062 K *1 3.546 L 2.456 M *2 1.490 N *2 1.238 ASSIGNED BY H-H AND C-H COSY.

     Hz     ppm     Int.

   3137.82   7.852     58
   3135.86   7.847    317
   3134.16   7.843    124
   3129.15   7.830    141
   3127.56   7.826    361
   3125.61   7.821     73
   2951.05   7.385    244
   2950.44   7.383    273
   2942.38   7.363    258
   2941.77   7.361    226
   2097.17   5.248    240
   1804.44   4.516     62
   1798.58   4.501    127
   1792.97   4.487    102
   1790.28   4.480    278
   1789.79   4.479    278
   1760.62   4.406     91
   1753.78   4.389    127
   1747.31   4.373     81
   1651.25   4.132    135
   1643.92   4.114    120
   1627.56   4.073    148
   1619.75   4.053    158
   1423.83   3.563     87
   1418.46   3.550     94
   1416.26   3.544     93
   1410.89   3.531     83
    981.81   2.457   1000
    595.70   1.491    874
    494.87   1.239    861
    494.51   1.238    850