parameter in CDCl3
parameter in DMSO-d6
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1H NMR 300 MHz C12 H9 N 5 wt% in CDCl3 pyrrolo(1,2-a)quinoline Parameter ppm Hz
D(A) 7.79 D(B) 6.76 D(C) 6.50 D(D) 7.269 D(E) 6.935 D(F) 7.586 D(G) 7.265 D(J) 7.442 D(K) 7.825 J(A,B) 2.9 J(A,C) 1.4 J(A,D) 0.7 J(A,E) 0.25 J(A,F) 0.0 J(A,G) 0.0 J(A,J) 0.0 J(A,K) 0.2 J(B,C) 3.8 J(B,D) 0.0 J(B,E) 0.0 J(B,F) 0.0 J(B,G) 0.0 J(B,J) 0.0 J(B,K) 0.0 J(C,D) -0.28 J(C,E) 0.28 J(C,F) 0.0 J(C,G) 0.0 J(C,J) 0.0 J(C,K) 0.0 J(D,E) 9.35 J(D,F) 0.34 J(D,G) 0.0 J(D,J) 0.29 J(D,K) 0.0 J(E,F) -0.37 J(E,G) 0.0 J(E,J) 0.0 J(E,K) 0.74 J(F,G) 7.83 J(F,J) 1.50 J(F,K) 0.54 J(G,J) 7.27 J(G,K) 1.11 J(J,K) 8.38 HEFFERNAN,M.L. & IRVINE,G.M. AUST.J.CHEM. 29, 837 (1976) J(A,B).J(A,C) AND J(B,C) : FROM SPECTRUM AT -20 C. J(A,D),J(A,E),J(A,K),J(C,D),J(C,E) : IN DMSO-D6
Hz ppm Int.
2351.82 7.839 489 2343.47 7.812 574 2338.79 7.796 477 2338.10 7.794 490 2337.45 7.791 485 2336.57 7.789 487 2335.92 7.786 496 2335.27 7.784 479 2280.53 7.602 403 2279.20 7.597 422 2272.76 7.576 472 2271.42 7.571 501 2241.25 7.471 287 2239.74 7.466 279 2233.96 7.447 411 2232.63 7.442 497 2231.46 7.438 285 2225.64 7.419 332 2224.13 7.414 303 2187.16 7.291 514 2185.97 7.287 1000 2179.41 7.265 569 2178.75 7.262 560 2178.35 7.261 546 2176.28 7.254 819 2172.13 7.240 299 2171.01 7.237 288 2084.99 6.950 768 2075.61 6.919 637 2031.38 6.771 629 2028.47 6.762 716 2027.61 6.759 779 2024.70 6.749 679 1952.53 6.508 603 1951.17 6.504 615 1948.75 6.496 565 1947.38 6.491 549
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1H NMR 300 MHz C12 H9 N 5 wt% in DMSO-d6 pyrrolo(1,2-a)quinoline Parameter ppm Hz
D(A) 8.215 D(B) 6.773 D(C) 6.541 D(D) 7.400 D(E) 7.087 D(F) 7.748 D(G) 7.365 D(J) 7.558 D(K) 8.208 J(A,B) 2.89 J(A,C) 1.44 J(A,D) 0.66 J(A,E) 0.25 J(A,F) 0.0 J(A,G) 0.0 J(A,J) 0.0 J(A,K) 0.25 J(B,C) 3.77 J(B,D) 0.0 J(B,E) 0.0 J(B,F) 0.0 J(B,G) 0.0 J(B,J) 0.0 J(B,K) 0.0 J(C,D) -0.28 J(C,E) 0.28 J(C,F) 0.0 J(C,G) 0.0 J(C,J) 0.0 J(C,K) 0.0 J(D,E) 9.33 J(D,F) 0.33 J(D,G) 0.30 J(D,J) 0.0 J(D,K) 0.0 J(E,F) -0.33 J(E,G) 0.0 J(E,J) 0.0 J(E,K) 0.62 J(F,G) 7.87 J(F,J) 1.52 J(F,K) 0.51 J(G,J) 7.24 J(G,K) 1.08 J(J,K) 8.42 HEFFERNAN,M.L. & IRVINE,G.M. AUST.J.CHEM 29, 837 (1976)
Hz ppm Int.
2466.52 8.222 956 2464.08 8.214 553 2462.72 8.209 502 2458.32 8.194 568 2329.17 7.764 402 2327.77 7.759 421 2321.29 7.738 463 2319.96 7.733 484 2276.13 7.587 263 2274.58 7.582 259 2268.85 7.563 379 2267.47 7.558 490 2266.24 7.554 289 2260.48 7.535 313 2258.95 7.530 297 2224.89 7.416 640 2215.88 7.386 1000 2209.17 7.364 538 2202.09 7.340 242 2201.14 7.337 238 2130.54 7.102 793 2121.21 7.071 647 2035.28 6.784 506 2032.32 6.774 637 2031.56 6.772 687 2028.64 6.762 563 1964.81 6.549 543 1963.45 6.545 558 1961.06 6.537 518 1959.68 6.532 496
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