16-Dehydroprogesterone

    Assign.     Shift(ppm)

      A             6.711
      B             5.736
      C             2.44
      D             2.44
      E          2.48 to 2.30
      F     *1      2.34
      G             2.30
      J             2.266
      K     *1      2.079
      L             2.029
      M             1.881
      N             1.764
      P             1.704
      Q             1.618
      R             1.548
      S             1.429
      T             1.339
      U             1.219
      V             1.122
      W             1.004
      X             0.944
     
     ASSIGNED BY H-H AND C-H COSY.
     J(A,F)=3.4HZ
     J(A,K)=1.8HZ
     J(D,T)=-12.7HZ
     J(D,R)=4.4HZ
     J(D,Q)=2.4HZ
     J(F,K)=-17.1HZ
     J(F,S)=6.5HZ
     J(G,V)=4.4HZ
     J(K,S)=12.1HZ
     J(L,P)=-13.4HZ
     J(M,N)=3.7HZ
     J(N,S)=11.6HZ
     J(N,W)=10.8HZ
     J(Q,T)=5.0HZ
     J(Q,R)=-14.0HZ
     J(Q,W)=5.2HZ
     J(R,W)=12.4HZ
     J(R,T)=12.4HZ
  

       ppm   Int.  Assign.

      199.34   572      1
      196.57   533      2
      170.80   695      3
      155.15   571      4
      144.01   846      5
      123.98   831      6
       55.70   886      7
       54.11   871      8
       46.08   754      9
       38.73   806     10
       35.56   790     11
       34.48   778     12
       33.94   886     13
       33.87  1000     14
       32.70   801     15
       32.10   780     16
       31.83   755     17
       27.08   667     18
       20.76   756     19
       17.21   671     20
       15.81   635     21
     
     ASSIGNED BY C-H COSY.