2,3-DIMETHYL-1-PENTANOL

Mass

MS-IW-3508          
2,3-dimethyl-1-pentanol
C7H16O              (Mass of molecular ion:    116)

   Source Temperature: 210 °C
   Sample Temperature: 160 °C
   Reservoir, 75 eV

      18.0       1.8
      26.0       1.2
      27.0      20.8
      28.0       6.2
      29.0      39.6
      30.0       1.7
      31.0      24.9
      39.0      18.5
      40.0       3.3
      41.0      78.6
      42.0      35.1
      43.0     100.0
      44.0       6.7
      45.0      39.2
      50.0       1.0
      51.0       1.9
      53.0       5.7
      54.0       1.9
      55.0      36.7
      56.0      94.3
      57.0      81.5
      58.0       7.5
      59.0      12.6
      60.0       1.8
      67.0       2.1
      68.0       2.8
      69.0      69.3
      70.0      23.6
      71.0       3.7
      73.0       2.3
      74.0       2.1
      83.0      42.1
      84.0      12.9
      85.0      82.4
      86.0       5.7
      87.0       2.1
      97.0       1.2
      98.0      15.3
      99.0       1.4

Assign. Shift(ppm) A 3.593 B 3.515 C 3.404 D 3.386 E 3.11 F 1.669 G 1.577 J 1.500 K 1.40 L 1.346 M 1.20 N 1.091 P 0.889 M 0.886 R 0.881 S 0.872 T 0.795 U 0.772 ASSIGNED BY H-H COSY TENTATIVE ASSIGNMENT FOR OPTICAL ISOMERS

     Hz     ppm     Int.

   1444.82   3.616     88
   1439.33   3.602     91
   1434.33   3.589    113
   1428.83   3.576    113
   1414.67   3.540    103
   1408.20   3.524    108
   1404.17   3.514    159
   1397.58   3.498    158
   1368.65   3.425    153
   1362.67   3.410    138
   1361.57   3.407    181
   1358.15   3.399    114
   1355.22   3.392    127
   1352.17   3.384    111
   1351.07   3.381    128
   1344.73   3.365     97
   1243.90   3.113    284
    368.77   0.923     32
    361.82   0.906    475
    359.01   0.899    820
    354.37   0.887    818
    352.05   0.881   1000
    346.80   0.868    412
    345.21   0.864    527
    321.29   0.804    744
    314.45   0.787    746
    312.13   0.782    737
    305.30   0.764    688
    295.53   0.740     31