Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Dichlorobis(triphenylphosphine)nickel(II)(14264-16-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Dichlorobis(triphenylphosphine)nickel(II)
Synonyms
Nickel, dichlorobis(triphenylphosphine)
Phosphine, tributyl-, compound with nickel chloride (2:1)
CAS
14264-16-5
Formula
C36H30Cl2NiP2
Molecular Weight
654.20000000000005
EINECS
238-154-8
RTECS
QR6170000
RTECS Class
Other
Beilstein/Gmelin
NA

Physical and Chemical Properties

Appearance
Dark gray solid.
Solubility in water
Insoluble

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Ingestion
No information found.
Inhalation
May cause respiratory tract irritation.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
EC Risk Phrase
R 45 34
EC Safety Phrase
S 53 45
UN (DOT)
3282

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.
Respirators
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code
15
Stability
No data.
Incompatibilities
Strong oxidizing agents, moisture.
Decomposition
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.

Transport Information

UN Number
3282
HS Code
2931 00 95
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