Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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3-Fluoronitrobenzene(402-67-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
3-Fluoronitrobenzene
Synonyms
3-Fluoronitrobenzene
m-Fluoronitrobenzene
CAS
402-67-5
Formula
C6H4FNO2
Molecular Weight
141.1
EINECS
206-953-0
Beilstein/Gmelin
1862210
Beilstein Reference
4-05-00-00719
EC Class
irritant

Physical and Chemical Properties

Appearance
Clear brown liquid.
Solubility in water
Insoluble
Melting Point
1.7
Boiling Point
205
Density
1.3272 g/cm3 (17.2 C)
Refractive Index
1.5262 (15 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a tightly closed container.
Handling
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
May cause respiratory tract irritation.
Skin
May cause skin irritation. May be absorbed through the skin. Absorption into the body may cause cyanosis. Effects may be delayed.
Eyes
May cause eye irritation.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes effects similar to those of acute skin absorption. Effects may be delayed 2 to 4 hours.
EC Risk Phrase
R 23/24/25 33
EC Safety Phrase
S 36/37 45
UN (DOT)
2810

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Laboratory experiments have resulted in mutagenic effects.

Fire Fighting Measures

Flash Point
76
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible Liquid. Containers may explode when heated. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Wash area with soap and water. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code
2
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong bases.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride, nitrogen, fluoride fumes.

Transport Information

UN Number
2810
HS Code
2904 90 85
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