Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Ethyl 4-piperidinecarboxylate(1126-09-6)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Ethyl 4-piperidinecarboxylate
Synonyms
4-(Ethoxycarbonyl)piperidine
4-Piperidinecarboxylic acid, ethyl ester
Ethyl 4-piperidinecarboxylate
Ethyl piperidine-4-carboxylate
Isonipecotic acid, ethyl ester
CAS
1126-09-6
Formula
C8H15NO2
Molecular Weight
157.21
EINECS
214-416-7
RTECS
NS5150000
Beilstein/Gmelin
118419
Beilstein Reference
4-22-00-00128

Physical and Chemical Properties

Appearance
Clear, colorless liquid.
Solubility in water
Very soluble
Boiling Point
204
Vapor Pressure
0.3 (25 C)
Density
1.019 g/cm3 (18 C)
pKa/pKb
3.71 (pKb)
Partition Coefficient
.91
Heat Of Vaporization
44.0 kJ/mol
Refractive Index
1.4591 (20 C)

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a cool, dry place. Keep container closed when not in use.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
May cause irritation of the digestive tract.
Inhalation
Causes respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
EC Risk Phrase
R 36/38
EC Safety Phrase
S 26 36
UN (DOT)
2810

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
80
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity

Disposal Code
1
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong bases.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Transport Information

UN Number
2810
HS Code
2933 39 99
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