Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
Home > Methyl bromoacetate > Methyl bromoacetate(96-32-2)

Methyl bromoacetate(96-32-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Methyl bromoacetate
Synonyms
Bromoacetic acid methyl ester
CAS
96-32-2
Formula
C3H5BrO2
Molecular Weight
152.97999999999999
EINECS
202-499-2
RTECS
AF6300000
RTECS Class
Other
Beilstein/Gmelin
506256
Beilstein Reference
4-02-00-00527
EC Class
toxic, irritant

Physical and Chemical Properties

Appearance
A colorless to straw-colored liquid with a sharp penetrating odor.
Solubility in water
Slightly soluble
Melting Point
-50
Boiling Point
145
Vapor Pressure
3.3 (25 C)
Density
1.6350 g/cm3 (20 C)
Partition Coefficient
.87
Heat Of Vaporization
39.1 kJ/mol
Usage
Used to make vitamins and pharmaceuticals.
Vapor Density
5.28
Refractive Index
1.4520 (20 C)

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.

Hazards Identification

Inhalation
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Inhalation at high concentrations may cause CNS depression and asphixiation. Harmful if inhaled.
Skin
May cause severe skin irritation. Harmful if absorbed through the skin. May cause dermatitis. May cause cyanosis of the extremities.
Eyes
May cause severe eye irritation. Lachrymator. May cause chemical conjunctivitis and corneal damage.
Ingestion
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Hazards
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
EC Risk Phrase
R 23/24/25 34
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
2643

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Effects may be delayed.
Poison Class
1

Fire Fighting Measures

Flash Point
60
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
Fire Potential
HIGHLY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Stability and Reactivity

Disposal Code
2
Incompatibilities
Acids, bases, oxidizing agents, reducing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2643
Hazard Class
6.1
Packing Group
II
HS Code
2915 90 80
Contact More