Home > Nickel fluoride > Nickel fluoride(10028-18-9)
Nickel fluoride(10028-18-9)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
Nickel fluoride
Nickel fluoride
Synonyms
Nickel difluoride
Nickel(II) fluoride (1:2)
Nickelous fluoride
Nickel difluoride
Nickel(II) fluoride (1:2)
Nickelous fluoride
CAS
10028-18-9
10028-18-9
Formula
F2Ni
F2Ni
Molecular Weight
96.68
96.68
EINECS
233-071-3
233-071-3
RTECS
QR6825000
QR6825000
RTECS Class
Mutagen
Mutagen
Merck
12,6591
12,6591
Beilstein/Gmelin
9246 (G)
9246 (G)
Physical and Chemical Properties
Appearance
Yellowish to green tetragonal crystals or yellow powder.
Yellowish to green tetragonal crystals or yellow powder.
Solubility in water
25 g/L
25 g/L
Melting Point
1360 - 1380
1360 - 1380
Vapor Pressure
0.076 (912 C)
0.076 (912 C)
Density
2.67 - 2.77 g/cm3 (25 C)
2.67 - 2.77 g/cm3 (25 C)
Usage
In battery cathodes.
In battery cathodes.
First Aid Measures
Ingestion
Seek medical assistance.
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Skin
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
Eyes
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Handling and Storage
Storage
Store in a cool, dry place. Store in a tightly closed container.
Store in a cool, dry place. Store in a tightly closed container.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards Identification
Inhalation
Respirations are first stimulated then depressed. Death is usually from respiratory paralysis. Following inhalation, coughing and choking may be noted.
Respirations are first stimulated then depressed. Death is usually from respiratory paralysis. Following inhalation, coughing and choking may be noted.
Skin
Urticaria and pruritus have been reported following exposure to fluoride.
Urticaria and pruritus have been reported following exposure to fluoride.
Eyes
See Inhalation.
See Inhalation.
Ingestion
Epigastric pain, nausea, dysphagia, salivation, hematemesis, and diarrhea may be noted. These effects may be delayed for several hours following exposure. Gi symptoms are noted when 3 to 5 mg/kg of fluoride are ingested.
Epigastric pain, nausea, dysphagia, salivation, hematemesis, and diarrhea may be noted. These effects may be delayed for several hours following exposure. Gi symptoms are noted when 3 to 5 mg/kg of fluoride are ingested.
UN (DOT)
3288
3288
Exposure Controls/Personal Protection
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Wear positive pressure self-contained breathing apparatus (SCBA).
Exposure Effects
Acute intoxication of nickel carbonyl has two stages, immediate and delayed. A person may have a temperature as a delayed symptom, but it will seldom elevate above 101 degrees. Hyperactive reflexes, painful muscle spasms, weakness and tetanic contractures may be noted due to fluoride induced hypocalcemia. Prenatal fluoride supplementation (2.2 mg NaF or 1 mg fluoride daily) during the last two trimesters of pregnancy has been reported to be safe.
Acute intoxication of nickel carbonyl has two stages, immediate and delayed. A person may have a temperature as a delayed symptom, but it will seldom elevate above 101 degrees. Hyperactive reflexes, painful muscle spasms, weakness and tetanic contractures may be noted due to fluoride induced hypocalcemia. Prenatal fluoride supplementation (2.2 mg NaF or 1 mg fluoride daily) during the last two trimesters of pregnancy has been reported to be safe.
Exposure limit(s)
IDHL: NIOSH considers nickel metal and other compounds (as Ni) to be a potential
IDHL: NIOSH considers nickel metal and other compounds (as Ni) to be a potential
Fire Fighting Measures
Fire Fighting
Use method most appropriate to fight surrounding fire.
Use method most appropriate to fight surrounding fire.
Fire Potential
Non-Combustible
Non-Combustible
Accidental Release Measures
Small spills/leaks
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Stability and Reactivity
Incompatibilities
Peroxides.
Peroxides.
Stability
Stable under normal temperatures and pressures.
Stable under normal temperatures and pressures.
Decomposition
Hydrogen fluoride, nickel oxide.
Hydrogen fluoride, nickel oxide.
Combustion Products
Toxic gases and vapors (such as nickel carbonyl) may be released in a fire involving nickel.
Toxic gases and vapors (such as nickel carbonyl) may be released in a fire involving nickel.
Transport Information
UN Number
3288
3288
Hazard Class
6.1
6.1
Packing Group
I; II; III
I; II; III
Contact
More
- Company Name:J & K SCIENTIFIC LTD.
- Tel:010-82848833 400-666-7788
- Fax:86-10-82849933
- WebSite:http://www.jkchemical.com
- Company Name:Alfa Aesar
- Tel:400-6106006
- Fax:021-67582001/03/05
- WebSite:http://chemicals.thermofisher.cn
- Company Name:Beijing HwrkChemical Technology Co., Ltd
- Tel:010-89508211 18501085097
- Fax:010-89508210
- WebSite:http://www.hwrkchemical.com
- Company Name:Energy Chemical
- Tel:021-021-58432009 400-005-6266
- Fax:021-58436166
- WebSite:http://www.energy-chemical.com
- Company Name:Shanghai Mintchem Development Co., Ltd
- Tel:021 6845 0923
- Fax:0086 20 8234 8082
- WebSite:http://www.mintchem.com/