Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2(2-Ethoxyethoxy)ethanol(111-90-0)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2(2-Ethoxyethoxy)ethanol
Synonyms
2-(2-Ethoxyethoxy) ethanol
Ethyl digol
Solvolsol
Transcutol
CAS
111-90-0
Formula
C6H14O3
Molecular Weight
134.18
EINECS
203-919-7
RTECS
KK8750000
RTECS Class
Mutagen; Reproductive Effector; Primary Irritant
Merck
13,1809
Beilstein/Gmelin
1736441
Beilstein Reference
4-01-00-02393

Physical and Chemical Properties

Appearance
Clear, colorless liquid with a mild, pleasant fruity odor, hygroscopic.
Solubility in water
Miscible
Melting Point
-80
Boiling Point
197
Vapor Pressure
0.13 (25 C)
Density
0.99 g/cm3 (20 C)
Partition Coefficient
-.54
Heat Of Vaporization
54.43 kJ/mol
Heat Of Combustion
-3515 kJ/mol
Usage
As solvent for cellulose esters, in lacquer & thinner formulations, in quick drying varnishes and enamels, for dyestuffs and wood stains.
Vapor Density
4.62
Saturation Concentration
184 ppm at 25 C (calculated)
Refractive Index
1.4273 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. Get medical aid.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.

Handling and Storage

Storage
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Use with adequate ventilation. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Store protected from light. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
Low hazard for usual industrial handling. May cause kidney damage.
Skin
May cause mild skin irritation.
Eyes
May cause eye irritation. May cause transient corneal injury. Causes redness and pain.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression. May be harmful if swallowed.
EC Risk Phrase
R 36
EC Safety Phrase
S 24 26

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A half-face organic vapor respirator may be worn for up to ten times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
Exposure Effects
CNS depression may occur.
Exposure limit(s)
OSHA PEL: 50 ppm Ceiling
Poison Class
-

Fire Fighting Measures

Flash Point
83
Autoignition
204
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible Liquid. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Cool containers with flooding quantities of water until well after fire is out.
Upper exp. limit
23.5
Lower exp. limit
1.2
Fire Potential
Combustible liquid and vapor.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code
1
Stability
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration.
Incompatibilities
Strong oxidizing agents, strong acids, isocyanates.
Decomposition
Carbon monoxide, carbon dioxide.
Combustion Products
Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.

Transport Information

HS Code
2909 44 00
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