Home > Methyltrichlorosilane > Methyltrichlorosilane(75-79-6)
Methyltrichlorosilane(75-79-6)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
Methyltrichlorosilane
Methyltrichlorosilane
Synonyms
[5-(Benzoylperoxy)-2,5-dimethylhexan-2-yl] benzenecarboperoxoate
2,5-Dimethyl-2,5-hexanedihydroperoxide dibenzoate
2,5-Dimethylhexane-2,5-diyl diperbenzoate
Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester
Kayaester AB
Luperox 118
Perhexa 25Z
Trichloro(methyl)silane
Trichloromethylsilane
[5-(Benzoylperoxy)-2,5-dimethylhexan-2-yl] benzenecarboperoxoate
2,5-Dimethyl-2,5-hexanedihydroperoxide dibenzoate
2,5-Dimethylhexane-2,5-diyl diperbenzoate
Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester
Kayaester AB
Luperox 118
Perhexa 25Z
Trichloro(methyl)silane
Trichloromethylsilane
CAS
2618-77-1
2618-77-1
CAS
75-79-6
75-79-6
Formula
C22H26O6
C22H26O6
Formula
CH3Cl3Si
CH3Cl3Si
Molecular Weight
386.44
386.44
Molecular Weight
149.47999999999999
149.47999999999999
EINECS
200-902-6
200-902-6
EINECS
220-050-9
220-050-9
RTECS
VV4550000
VV4550000
RTECS Class
Primary Irritant
Primary Irritant
Beilstein/Gmelin
1361381
1361381
Beilstein/Gmelin
3451013
3451013
Beilstein Reference
3-09-00-01050
3-09-00-01050
Beilstein Reference
4-04-00-04212
4-04-00-04212
EC Index Number
014-004-00-5
014-004-00-5
EC Class
Reacts violently with water; Highly flammable; Irritant
Reacts violently with water; Highly flammable; Irritant
Physical and Chemical Properties
Appearance
A colorless fuming liquid with a pungent odor.
A colorless fuming liquid with a pungent odor.
Appearance
It is generally stored or transported as a mixture, with an inert solid.
It is generally stored or transported as a mixture, with an inert solid.
Solubility in water
Decomposes
Decomposes
Solubility in water
Insoluble
Insoluble
Melting Point
-90
-90
Melting Point
117
117
Boiling Point
66
66
Vapor Pressure
167
167
Density
1.27 g/cm3 (20 C)
1.27 g/cm3 (20 C)
Partition Coefficient
4.19
4.19
Heat Of Vaporization
30.2 kJ/mol
30.2 kJ/mol
Heat Of Combustion
-1014 kJ/mol
-1014 kJ/mol
Usage
Intermediate for silicones.
Intermediate for silicones.
Vapor Density
5.17
5.17
Odor threshold
as hydrochloric acid - 1 ppm
as hydrochloric acid - 1 ppm
Refractive Index
1.412 (20 C)
1.412 (20 C)
First Aid Measures
Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Ingestion
Seek medical assistance.
Seek medical assistance.
Inhalation
Causes irritation.
Causes irritation.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
May cause severe injury or burns.
May cause severe injury or burns.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Skin
Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes.
Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes.
Eyes
See Skin.
See Skin.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Eyes
Immediately flush with running water for at least 20 minutes.
Immediately flush with running water for at least 20 minutes.
Handling and Storage
Storage
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Flammables-area.
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Flammables-area.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Do not allow contact with water. Use only in a chemical fume hood.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Do not allow contact with water. Use only in a chemical fume hood.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards Identification
Ingestion
Aspiration hazard. May be harmful if swallowed.
Aspiration hazard. May be harmful if swallowed.
Ingestion
See Skin.
See Skin.
Inhalation
Causes respiratory tract irritation. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Causes respiratory tract irritation. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Skin
Causes severe skin irritation. Harmful if absorbed through the skin. Substance is rapidly absorbed through the skin. Causes redness and pain.
Causes severe skin irritation. Harmful if absorbed through the skin. Substance is rapidly absorbed through the skin. Causes redness and pain.
Eyes
Causes severe eye irritation. May cause blindness. Causes redness and pain.
Causes severe eye irritation. May cause blindness. Causes redness and pain.
Hazards
May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames. May burn rapidly with flare-burning effect. Containers may explode when heated. Runoff may create fire or explosion hazard.
May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames. May burn rapidly with flare-burning effect. Containers may explode when heated. Runoff may create fire or explosion hazard.
Hazards
Toxic hydrogen chloride and phosgene gases may form in fires. Reacts with water or steam to form hydrochloric acid. Vapor forms flammable mixture with air. May form explosive mixture in air. Avoid contact with water or moist air.
Toxic hydrogen chloride and phosgene gases may form in fires. Reacts with water or steam to form hydrochloric acid. Vapor forms flammable mixture with air. May form explosive mixture in air. Avoid contact with water or moist air.
EC Risk Phrase
R 11 14 36/37/38
R 11 14 36/37/38
EC Safety Phrase
S 26 39
S 26 39
UN (DOT)
1250
1250
UN (DOT)
2172
2172
UN (DOT)
2173
2173
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Wear positive pressure self-contained breathing apparatus (SCBA).
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Poison Class
3
3
Fire Fighting Measures
Flash Point
-15
-15
Autoignition
> 500
> 500
Fire Fighting
SMALL FIRES: Water spray or fog is preferred; if water not available use dry chemical, carbon dioxide or regular foam. LARGE FIRES: Flood fire area with water from a distance. Use water spray or fog; do not use straight streams. Move containers from fire area if you can do it without risk. Do not move cargo or vehicle if cargo has been exposed to heat. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SMALL FIRES: Water spray or fog is preferred; if water not available use dry chemical, carbon dioxide or regular foam. LARGE FIRES: Flood fire area with water from a distance. Use water spray or fog; do not use straight streams. Move containers from fire area if you can do it without risk. Do not move cargo or vehicle if cargo has been exposed to heat. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
Upper exp. limit
10.4
10.4
Lower exp. limit
5.5
5.5
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Fire Potential
May be ignited by heat, sparks or flames. May burn rapidly with flare-burning effect.
May be ignited by heat, sparks or flames. May burn rapidly with flare-burning effect.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Small spills/leaks
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep substance wet using water spray. Stop leak if you can do it without risk. SMALL SPILLS: Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep substance wet using water spray. Stop leak if you can do it without risk. SMALL SPILLS: Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal.
Stability and Reactivity
Stability
No data.
No data.
Incompatibilities
Organic compounds can ignite on contact with concentrated peroxides, strongly reduced material such as sulfides, nitrides, and hydrides
Organic compounds can ignite on contact with concentrated peroxides, strongly reduced material such as sulfides, nitrides, and hydrides
Incompatibilities
Strong acids - strong bases - strong oxidizing agents - alcohols - chemically active metals (potassium, magnesium, sodium, zinc) - alkalis.
Strong acids - strong bases - strong oxidizing agents - alcohols - chemically active metals (potassium, magnesium, sodium, zinc) - alkalis.
Stability
Unstable.
Unstable.
Disposal Code
24
24
Decomposition
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, silicon oxide.
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, silicon oxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.
Fire will produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
1250
1250
UN Number
2172
2172
UN Number
2173
2173
Hazard Class
3
3
Hazard Class
5.2
5.2
Packing Group
I
I
HS Code
2931 00 95
2931 00 95
Contact
More
- Company Name:Shandong Luoheng Chemical Products Co. , Ltd.
- Tel: 17362288188
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- Company Name:Shanghai Aladdin Bio-Chem Technology Co.,LTD
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- WebSite:https://www.chemicalbook.com/ShowSupplierProductsList1502108/0.htm
- Company Name:tonsooh
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- Company Name:Hubei coward chemical co .，ltd
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