Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Triallylamine(102-70-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Triallylamine
Synonyms
N,N-di-2-Propenyl-2-propen-1-amine
Tri-2-propenylamine
CAS
102-70-5
Formula
C9H15N
Molecular Weight
137.25
EINECS
203-048-2
RTECS
XX5950000
RTECS Class
Human Data; Primary Irritant
Beilstein/Gmelin
1740881
Beilstein Reference
4-04-00-01061

Physical and Chemical Properties

Appearance
A colorless liquid with a fishlike odor.
Solubility in water
2.5 g/L
Boiling Point
150
Vapor Pressure
4 (25 C)
Density
0.796 g/cm3
pKa/pKb
5.69 (pKb)
Partition Coefficient
2.59
Heat Of Vaporization
39.4 kJ/mol
Usage
Chemical intermediate for ion exchange resins & rubber.
Odor threshold
0.5 ppm.
Refractive Index
1.4486 (20 C)

First Aid Measures

Ingestion
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage

Storage
In general, materials which are toxic as stored or which can decomp into toxic components should be stored in a cool, well-ventilated place, out of direct rays of the sun, away from areas of high fire hazard, and should be periodically inspected. Incompatible materials should be isolated from each other.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion
Nausea, vomiting and diarrhea are possible if ingested.
Inhalation
Cough, tachypnea, and wheezing are common after inhalation.
Skin
Redness, swelling and pain may occur.
Eyes
Irritants may cause swelling, redness and pain at any site, especially at mucous membranes. The mouth, nose, and eyes are susceptible to these effects.
Hazards
May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
EC Risk Phrase
R 10 22 23/24 34
EC Safety Phrase
S 26 28 36/37/39 45
UN (DOT)
2610

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Poison Class
3

Fire Fighting Measures

Flash Point
30
Autoignition
204
Fire Fighting
Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
Fire Potential
Flammable/combustible material.

Accidental Release Measures

Small spills/leaks
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.

Stability and Reactivity

Stability
No data.
Incompatibilities
Reacts violently with oxidizing agents Corrosive towards Al and Zn Incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides.
Decomposition
When heated to decomposition it emits toxic fumes of nitrogen oxides.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2610
Hazard Class
3
Packing Group
III
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