Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Ethyl orthoformate(122-51-0)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Ethyl orthoformate
Synonyms
1,1,1-[Methylidynetris(oxy)]tris[ethane]
Orthoformic acid, triethyl ester
Triethoxymethane
Triethyl orthoformate
CAS
122-51-0
Formula
C7H16O3
Molecular Weight
148.19999999999999
EINECS
204-550-4
RTECS
RM6475000
RTECS Class
Primary Irritant
Merck
12,7012
Beilstein/Gmelin
605384
Beilstein Reference
4-02-00-00025
EC Class
flammable

Physical and Chemical Properties

Appearance
A clear, colorless liquid with a pungent odor.
Solubility in water
Slightly soluble
Melting Point
-61
Boiling Point
146
Vapor Pressure
4.8 (25 C)
Density
0.8964 g/cm3
Partition Coefficient
.16
Heat Of Vaporization
44.30 kJ/mol
Heat Of Combustion
-4366 kJ/mol
Usage
Used to make other chemicals.
Vapor Density
5.11
Refractive Index
1.39105 (15 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
May cause irritation of the digestive tract.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
EC Risk Phrase
R 10 36
EC Safety Phrase
S 16 26 36
UN (DOT)
2524

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
The toxological properties of this substance have not been fully investigated.
Poison Class
4

Fire Fighting Measures

Flash Point
35
Autoignition
180
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Extinguishing media: Use water spray to cool fire-exposed containers. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, water spray or regular foam. Cool containers with flooding quantities of water until well after fire is out. For large fires, use water spray, fog or regular foam.
Upper exp. limit
25.1
Lower exp. limit
.7
Fire Potential
HIGHLY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Stability and Reactivity

Disposal Code
1
Incompatibilities
Oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2524
Hazard Class
3
Packing Group
III
HS Code
2915 90 80
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