Aluminium bromide(7727-15-3)

Product Name
Aluminium bromide

Synonyms
Aluminum tribromide
Tribromoalumane
Tribromoaluminum

CAS
7727-15-3

Formula
AlBr3

Molecular Weight
266.70999999999998

EINECS
231-779-7

RTECS
BD0350000

RTECS Class
Other

Merck
13,330

Beilstein/Gmelin
2192 (G)

Beilstein/Gmelin
NA

EC Class
harmful, corrosive

Appearance
A white to yellowish-red, lumpy solid with a pungent odor.

Solubility in water
Reacts

Melting Point
97

Boiling Point
265

Vapor Pressure
12 (120 C)

Density
3.2 g/cm3

Usage
Acid catalyst in organic synthesis.

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Ingestion
Seek immediate medical attention.

Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Inhalation
Inhalation is unlikely. Emergency treatment would be to remove victim from exposure and seek medical attention.

Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. If water-reactive products are embedded in the skin, no water should be applied. The embedded products should be covered with a light oil.

Skin
Unlikely that emergency treatment will be required. If adverse effects oddur, wash with soap and mild detergent and large amounts of water or normal saline. Seek edical attention.

Eyes
Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes
Unlikely. Wash with large quantities of water or normal sailine.

Storage
Keep container closed when not in use. Keep away from water. Corrosives area. Refrigerator (approx 4 C). Store protected from moisture.

Storage
Keep in a cool, dry location, well isolated from heat and sources of ignition.

Handling
Use only in a well ventilated area. Do not allow water to get into the container because of violent reaction. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.

Handling
Avoid heat and sources of ignition.

Inhalation
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.

Skin
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.

Eyes
Contact with eyes may cause severe irritation, and possible eye burns. When substances becomes wet or comes in contact with moisture of the mucous membranes, it becomes an irritant. May cause chemical conjunctivitis and corneal damage.

Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May be harmful if swallowed. May cause systemic effects. Aluminum may be readily absorbed from the gastrointestinal tract.

Hazards
May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.)Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.

Hazards
Avoid inhalation of material or combustion products.

EC Risk Phrase
R 14 22 34

EC Safety Phrase
S 26 36/37/39 43 45

UN (DOT)
1725

UN (DOT)
3270

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Personal Protection
Protective gloves are not normally required. Protective eyewear is always advised.

Respirators
No respirator is required under normal conditions of use.

Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects
No information on significant adverse effects resulting from ingestion, inhalation, eyes or skin.

Exposure Effects
Effects may be delayed. Chronic ingestion of aluminum oxide may produce loss of appetite, hemolysis, renal deposition and bone marrow damage

Exposure limit(s)
OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3

Poison Class
2 (Very strong toxins)

Fire Fighting
Extinguish fire using regular dry chemical extinguisher, sand, earth, foam or water. Move containers from fire area if it can be done without risk. Cool container with water spray until fire is out.

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use water spray to keep fire-exposed containers cool. May ignite or explode on contact with steam or moist air. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Combustible material; may burn but does not ignite readily. Extinguishing media: Do NOT get water inside containers. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. For small fires, use dry chemical or carbon dioxide. For large fires, flood fire area with large quantities of water, while knocking down vapors with water fog.

Fire Potential
Flammable solid. Severe fire hazard.

Fire Potential
May burn but does not ignite readily.

Small spills/leaks
Avoid heat and sources of ignition. Collect material and place in suitable, loosely covered container for disposal. Isolate from sources of ignition.

Small spills/leaks
Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not expose spill to water.

Disposal Code
24

Incompatibilities
Moisture, acids, alcohols.

Incompatibilities
Oxidizing materials.

Stability
Stable at normal temperatures and pressures.

Stability
Stable under normal temperatures and pressures. Combines vigorously or explosively with water.

Decomposition
Hydrogen bromide, aluminum oxide.

Decomposition
Oxides of carbon and nitrogen.

Combustion Products
Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air.

UN Number
3270

UN Number
1725

Hazard Class
4.1

Hazard Class
8

Packing Group
II

HS Code
2827 59 00