Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Propionyl chloride(79-03-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Propionyl chloride
Synonyms
1aH,5aH-Tropan-3-one
3-Tropinone
8-Azabicyclo[3.2.1]octan-3-one, 8-methyl-
8-Methyl-8-azabicyclo[3.2.1]octan-3-one
Caprinic alcohol
Decan-1-ol
Decyl alcohol
N-Methyl-8-azabicyclo[3.2.1]octan-3-one
Tropinone
CAS
112-30-1
CAS
532-24-1
Formula
C10H22O
Formula
C8H13NO
Molecular Weight
139.19999999999999
Molecular Weight
158.29
EINECS
203-956-9
EINECS
208-530-6
RTECS
HE4375000
RTECS Class
Agricultural Chemical and Pesticide; Tumorigen; Reproductive Effector; Natural Product; Primary Irritant
Merck
13,2875
Beilstein/Gmelin
1735221
Beilstein/Gmelin
2329
Beilstein Reference
4-01-00-01815
Beilstein Reference
5-21-07-00032
EC Class
irritant

Physical and Chemical Properties

Appearance
Beige to brown crystalline powder.
Appearance
Colorless to light yellow liquid, with odor resembling orange flowers.
Solubility in water
Very soluble
Solubility in water
0.036 g/L (25 C)
Melting Point
41 - 42
Melting Point
7
Boiling Point
217
Boiling Point
230
Vapor Pressure
0.015 (25 C)
Vapor Pressure
0.14 (25 C)
Density
0.82634 g/cm3
Density
0.9872 g/cm3 (99.6 C)
pKa/pKb
5.07 (pKb)
Partition Coefficient
.07
Partition Coefficient
4.57
Heat Of Vaporization
45.4 kJ/mol
Heat Of Vaporization
61.5 kJ/mol
Heat Of Combustion
-6600 kJ/mol
Usage
Alkaloid.
Usage
Plant growth regulator.
Vapor Density
5.46
Saturation Concentration
6.7-10.8 ppm at 20-25 C (6)
Refractive Index
1.4338 (25 C)
Refractive Index
1.4598 (100 C)

First Aid Measures

Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Inhalation
Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth. Aspiration may lead to pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
Skin
Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause cyanosis of the extremities.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Causes severe eye irritation. May cause chemical conjunctivitis and corneal damage. May cause chemical conjunctivitis.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances.
Storage
Keep container closed when not in use. Store in a tightly closed container. Refrigerator (approx 4 C).
Handling
Wash hands before eating. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Avoid contact with heat, sparks and flame. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 20 36/38
EC Risk Phrase
R 20/21/22
EC Safety Phrase
S 22 36/37/39
EC Safety Phrase
S 26 36/37/39
UN (DOT)
1544
UN (DOT)
1986

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Prolonged or repeated skin contact may cause dermatitis. Prolonged exposure may produce a narcotic effect. Effects may be delayed.
Poison Class
-

Fire Fighting Measures

Flash Point
82
Flash Point
90
Autoignition
255
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Can form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dusts may be combustible when exposed to heat, flame, or oxidizing agents. Runoff from fire control or dilution water may cause pollution. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire.
Upper exp. limit
5.5
Lower exp. limit
.7
Fire Potential
Combustible Liquid. Moderate when exposed to heat or flame, can react with oxidizing materials.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code
1
Incompatibilities
Oxidizing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Combustion Products
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

Transport Information

UN Number
1544
UN Number
1986
Hazard Class
3
Packing Group
I; II; III
HS Code
2905 19 00
HS Code
2939 99 90
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