Home > 1,1,1,3,3,3-Hexafluoro-2-propanone > 1,1,1,3,3,3-Hexafluoro-2-propanone(684-16-2)
1,1,1,3,3,3-Hexafluoro-2-propanone(684-16-2)
Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
1,1,1,3,3,3-Hexafluoro-2-propanone
1,1,1,3,3,3-Hexafluoro-2-propanone
Synonyms
1,1,1,3,3,3-Hexafluoroacetone
2-Propanone, 1,1,1,3,3,3-hexafluoro
Hexafluoro-2-propanone
Perfluoroacetone
1,1,1,3,3,3-Hexafluoroacetone
2-Propanone, 1,1,1,3,3,3-hexafluoro
Hexafluoro-2-propanone
Perfluoroacetone
CAS
684-16-2
684-16-2
Formula
C3F6O
C3F6O
Molecular Weight
166.03
166.03
EINECS
211-676-3
211-676-3
RTECS
UC2450000
UC2450000
RTECS Class
Reproductive Effector
Reproductive Effector
Beilstein/Gmelin
607236
607236
Beilstein Reference
4-01-00-03215
4-01-00-03215
Physical and Chemical Properties
Appearance
Colorless gas. Musty odor becomes acrid in presence of acidic impurities.
Colorless gas. Musty odor becomes acrid in presence of acidic impurities.
Solubility in water
Insoluble
Insoluble
Melting Point
-129
-129
Boiling Point
-26
-26
Vapor Pressure
5010 (25 C)
5010 (25 C)
Density
1.65 g/cm3 (25 C)
1.65 g/cm3 (25 C)
Partition Coefficient
1.89
1.89
Heat Of Vaporization
22.5 kJ/mol
22.5 kJ/mol
Usage
Chemical intermediate for hexafluoroisopropanol, polyacrylates for textile coating & polyester coating for textiles, solvent for acetal resins & polyamides, polymer adhesive.
Chemical intermediate for hexafluoroisopropanol, polyacrylates for textile coating & polyester coating for textiles, solvent for acetal resins & polyamides, polymer adhesive.
Vapor Density
1.65
1.65
First Aid Measures
Ingestion
Administer milk, calcium gluconate, or calcium lactate to bind fluoride ion in the gastrointestinal tract. Antacids (aluminum and/or magnesium based) should be administered. Iv calcium (gluconate or chloride) and magnesium may be necessary to correct serum deficits of these divalent metals in serious overdosage. Monitor ekg and vital signs.
Administer milk, calcium gluconate, or calcium lactate to bind fluoride ion in the gastrointestinal tract. Antacids (aluminum and/or magnesium based) should be administered. Iv calcium (gluconate or chloride) and magnesium may be necessary to correct serum deficits of these divalent metals in serious overdosage. Monitor ekg and vital signs.
Inhalation
Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
Skin
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
Eyes
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Handling and Storage
Storage
Store in tightly closed container in a cool location.
Store in tightly closed container in a cool location.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards Identification
Ingestion
Epigastric pain, nausea, dysphagia, salivation, hematemesis, and diarrhea may be noted. These effects may be delayed for several hours following exposure. Gi symptoms are noted when 3 to 5 mg/kg of fluoride are ingested.
Epigastric pain, nausea, dysphagia, salivation, hematemesis, and diarrhea may be noted. These effects may be delayed for several hours following exposure. Gi symptoms are noted when 3 to 5 mg/kg of fluoride are ingested.
Inhalation
Respirations are first stimulated then depressed. Death is usually from respiratory paralysis. Following inhalation, coughing and choking may be noted.
Respirations are first stimulated then depressed. Death is usually from respiratory paralysis. Following inhalation, coughing and choking may be noted.
Skin
Urticaria and pruritus have been reported following exposure to fluoride.
Urticaria and pruritus have been reported following exposure to fluoride.
Eyes
See Skin.
See Skin.
Hazards
Vapors from liquefied gas are initially heavier than air and spread along ground. Some of these materials may react violently with water. Containers may explode when heated. Ruptured cylinders may rocket.
Vapors from liquefied gas are initially heavier than air and spread along ground. Some of these materials may react violently with water. Containers may explode when heated. Ruptured cylinders may rocket.
EC Risk Phrase
R 14 23/25 37/38 41 44
R 14 23/25 37/38 41 44
EC Safety Phrase
S 23 26 36/37/39 45
S 23 26 36/37/39 45
UN (DOT)
2420
2420
Exposure Controls/Personal Protection
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Wear positive pressure self-contained breathing apparatus (SCBA).
Exposure limit(s)
TLV: 0.1 ppm; 0.68 mg/m3 (as TWA) (skin) (ACGIH 1992-1993) NIOSH REL: TWA 0.1 ppm (0.7 mg/m3) skin
TLV: 0.1 ppm; 0.68 mg/m3 (as TWA) (skin) (ACGIH 1992-1993) NIOSH REL: TWA 0.1 ppm (0.7 mg/m3) skin
Poison Class
3
3
Fire Fighting Measures
Flash Point
-24
-24
Fire Fighting
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use alcohol foam, dry chemical or carbon dioxide. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Keep run-off water out of sewers and water sources.
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use alcohol foam, dry chemical or carbon dioxide. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Keep run-off water out of sewers and water sources.
Fire Potential
May burn but does not ignite readily.
May burn but does not ignite readily.
Accidental Release Measures
Small spills/leaks
Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.
Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.
Stability and Reactivity
Stability
No data.
No data.
Incompatibilities
Reacts with many acids and bases liberating heat and flammable gases (e.g., H2) Reacts with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides Reacts violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Reacts with many acids and bases liberating heat and flammable gases (e.g., H2) Reacts with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides Reacts violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Decomposition
Toxic fumes are formed when this material is heated. Reacts with water or acids, producing heat and highly toxic fumes.
Toxic fumes are formed when this material is heated. Reacts with water or acids, producing heat and highly toxic fumes.
Combustion Products
Emits toxic and/or explosive gases under fire conditions.
Emits toxic and/or explosive gases under fire conditions.
Transport Information
UN Number
2420
2420
Hazard Class
2.3
2.3