Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Chlorotributyltin(1461-22-9)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Chlorotributyltin
Synonyms
Chlorotributyltin
Tributylchlorotin
CAS
1461-22-9
Formula
C12H27ClSn
Molecular Weight
325.49
EINECS
215-958-7
RTECS
WH6820000
RTECS Class
Agricultural Chemical and Pesticide; Organometallic; Mutagen; Reproductive Effector; Primary Irritant
Beilstein/Gmelin
3535715
Beilstein Reference
4-04-00-04330
EC Index Number
050-008-00-3
EC Class
toxic, irritant, dangerous for the environment

Physical and Chemical Properties

Appearance
Clear, colorless liquid.
Solubility in water
Insoluble
Melting Point
-9
Boiling Point
171
Vapor Pressure
0.075 (20 C)
Density
1.20 g/cm3 (20 C)
Usage
Antifoulant, microbiocide.
Vapor Density
11.2
Refractive Index
1.49 (20 C)

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Handling
Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.

Hazards Identification

Inhalation
May cause respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 21 25 36/38 48/23/25 50/53
EC Safety Phrase
S 35 36/37/39 45 60 61
UN (DOT)
2788

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Reproductive effects have been reported in animals.
Exposure limit(s)
OSHA TWA: 0.1 mg/m3
Poison Class
3

Fire Fighting Measures

Flash Point
>100
Autoignition
> 150
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code
24
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Strong oxidizing agents.
Decomposition
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, tin/tin oxides.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2788
Hazard Class
6.1
Packing Group
I; II; III
HS Code
2931 00 95
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