| CAS: | 10026-11-6 |
| MF: | Cl4Zr |
| MW: | 233.04 |
| EINECS: | 233-058-2 |
| Product Categories: | material;construction;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Chemical;metal halide;Materials Science;Metal and Ceramic Science;Salts;Zirconium;Zirconium Salts |
| Mol File: | 10026-11-6.mol |
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| Zirconium tetrachloride Chemical Properties |
| Melting point | 437 °C |
| Boiling point | 331°C |
| density | 2.8 g/mL at 25 °C(lit.) |
| vapor pressure | 1 mm Hg ( 190 °C) |
| storage temp. | Store below +30°C. |
| solubility | Soluble in alcohol, ether, hydrochloric acid. |
| form | powder |
| color | White |
| Specific Gravity | 2.803 |
| PH | <1 (H2O, 20℃)(saturated aqueous solution) |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive & Hygroscopic |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,10174 |
| Exposure limits | ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
| CAS DataBase Reference | 10026-11-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Zirconium tetrachloride(10026-11-6) |
| EPA Substance Registry System | Zirconium tetrachloride (10026-11-6) |
| Zirconium tetrachloride Usage And Synthesis |
| Chemical Properties | White, lustrous crystals. Sublimes above 300C. Soluble in alcohol; decomposes in water.
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| Chemical Properties | Zirconium tetrachloride forms lustrous, white, monoclinic crystals that melt at 437 ℃. It is a corrosive powder. It is hygroscopic, and thus soluble in cold water, alcohol, ether, and concentrated hydrochloric acid. It reacts vigorously with water forming hydrogen chloride (irritating vapor) and zirconium oxychloride. When moist, zirconium tetrachloride reacts with common materials to form hydrochloric acid that is corrosive to many metals. Through hydrolysis to HCl, zirconium tetrachloride can irritate the respiratory tract and other superficial surfaces of the body on exposure. Zirconium tetrachloride readily forms coordinate bonds with oxygen and nitrogen in organic molecules. |
| Physical properties | White monoclinic crystals; hygroscopic; density 2.80 g/cm3; sublimes at 331°C; triple point 437°C; vapor pressure 1 torr at 190°C; critical temperature 504.85°C; critical pressure 56.95 atm; critical volume 319 cm3/mol; decomposed by water; soluble in alcohol, ether, and concentrated hydrochloric acid. |
| Uses | Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry. |
| Uses | For applications in organozirconium chemistry.
1. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
2. Zirconium (IV) chloride is used as an efficient catalyst in the Pechmann condensation reaction of phenols with β‐keto esters leading to the formation of coumarin derivatives in good yields under solvent‐free conditions. |
| Uses | Zirconium(IV) chloride (ZrCl4) is a Lewis acid catalyst, which has low toxicity. It is a moisture resistant material that is used as a catalyst in organic transformations.
ZrCl4 can be used as a catalyst for a variety of organic syntheses, such as Friedel-Crafts reaction, condensation reaction and other reduction reactions. |
| Uses | Friedel-Crafts catalyst. Component of Ziegler-type catalysts in the condensation of ethylene. Starting material in the synthesis of a number of organic derivatives of zirconium, such as alkoxides and zircocene. The alkoxides have been shown to be of value in the curing of silicone plastic films. The alkoxyzirconium carboxylates are said to be useful in the water-repellent treatment of textiles and other fibrous materials. |
| Definition | ChEBI: Zirconium tetrachloride is a zirconium coordination entity comprising four chlorine atoms bound to a central zirconium atom. It has a role as a catalyst. It is a zirconium coordination entity and an inorganic chloride. |
| Preparation | Zirconium tetrachloride is obtained as an intermediate in recovering zirconium metal from zircon and other minerals (See Zirconium, Recovery). The tetrachloride is obtained by heating a mixture of zirconium hydroxide and car 1004 bon with chlorine gas
Also, tetrachloride can be made by reacting zirconium hydroxide with hydrochloric acid: Zr(OH)4 + 4HCl → ZrCl4 + 4H2O. |
Packing &shipping&Payment
Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
| Quantity(Kilograms) | 1 - 10000 | >10000 |
| Est. Time(days) | 5 | To be negotiated |
Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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