(R)-DM-BINAP

Product Name:

(R)-DM-BINAP

Synonyms:

(R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP;(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP);(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;RAC-XYLYL-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL

CAS:

MF:

C52H48P2

MW:

734.89

EINECS:

681-153-6

Product Categories:

BINAP Series;Chiral Phosphine

Mol File:

137219-86-4.mol

 

(R)-DM-BINAP Chemical Properties

Melting point 

203-206°C

alpha 

169 º (c=1 in chloroform)

form 

crystal

color 

white to pale yellow

optical activity

[α]20/D +169°, c = 1 in chloroform

 

Safety Information

WGK Germany 

3

Reaction

1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
2. Ligand used in the enantioselective fluorination of oxindoles.
3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
5. Asymmetric hydroboration of unsaturated imines.