1-Chlorobutane

$ 1.00 /1kg

Min. Order1g
Purity99%
Cas No109-69-3
Supply Ability100KG
Update time2019-07-06

career henan chemical co

7YR

China

Chemical Properties

Product Name	1-Chlorobutane
CAS No	109-69-3
EC-No
Min. Order	1g
Purity	99%
Supply Ability	100KG
Release date	2019/07/06

1-Chlorobutane Basic information

Product Name:	1-Chlorobutane
Synonyms:	1-CHLOROBUTANE;BUTYL CHLORIDE;CHLOROBUTANE;S3, N-BUTYL CHLORIDE;N-PROPYLCARBINYL CHLORIDE;N-BUTYL CHLORIDE;1-chlorobutane B&J brand 4 L;1-butyl chloride
CAS:	109-69-3
MF:	C4H9Cl
MW:	92.57
EINECS:	203-696-6
Product Categories:	Pharmaceutical Intermediates;Organics;CHLORO ALKANE COMPOUNDS;Alkyl Chlorides;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes;Anhydrous Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Sure/Seal Bottles;API Intermediate
Mol File:	109-69-3.mol

1-Chlorobutane Chemical Properties

Melting point	-123 °C
Boiling point	77-78 °C(lit.)
density	0.886 g/mL at 25 °C(lit.)
vapor density	3.2 (vs air)
vapor pressure	80.1 mm Hg ( 78.4 °C)
refractive index	n20/D 1.402(lit.)
Fp	-12 °F
storage temp.	2-8°C
solubility	water: soluble0.11g/L at 20°C
form	Viscous Liquid
color	White to pink to light brown
explosive limit	1.8-10.1%(V)
Water Solubility	0.5 g/L (20 ºC)
Merck	14,1560
BRN	1730909
Stability:	Stable. Highly flammable. Note low flash point and wide explosion limit range. Incompatible with strong oxidizing agents, strong bases.
InChIKey	VFWCMGCRMGJXDK-UHFFFAOYSA-N
CAS DataBase Reference	109-69-3(CAS DataBase Reference)
NIST Chemistry Reference	Butane, 1-chloro-(109-69-3)
EPA Substance Registry System	Butane, 1-chloro-(109-69-3)

Safety Information

Hazard Codes	F
Risk Statements	11
Safety Statements	9-16-29
RIDADR	UN 1127 3/PG 2
WGK Germany	2
RTECS	EJ6300000
F	1-10
TSCA	Yes
HazardClass	3
PackingGroup	II
HS Code	29031990
Hazardous Substances Data	109-69-3(Hazardous Substances Data)
Toxicity	LD50 orally in rats: 2.67 g/kg (Smyth)

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

1-Chlorobutane Usage And Synthesis

Chemical Properties	colourless liquid
Uses	As butylating agent in organic synthesis, e.g., in the manufacture of butyl cellulose.
General Description	A water white liquid with a sharp odor. Flash point 20°F. Boiling point 77-78°C (173°F). Density 7.5 lb / gal. Slightly soluble in water. Vapors are heavier than air. Used in the manufacture of a variety of organic chemicals.
Air & Water Reactions	Highly flammable. May react with atmospheric moisture over prolonged periods of exposure. Slightly soluble in water.
Reactivity Profile	1-Chlorobutane is incompatible with oxidizing agents and strong bases. Reacts with aluminum powder, liquid oxygen, potassium and sodium . Emits phosgene gas when heated to decomposition,. Reacts with aluminum and magnesium. May be sensitive to heat.
Health Hazard	Mildly irritating to the skin and eyes, liquid may cause rash due to removal of skin oils. Ingestion or skin absorbtion may cause intestinal upset, cramping, and central nervous system depression.
Fire Hazard	Special Hazards of Combustion Products: May produce phosgene gas in fire
Safety Profile	Moderately toxic by ingestion. Mutation data reported. See CHLORINATED HYDROCARBONS, ALIPHATIC. Skin and eye irritant. Dangerous fire hazard when exposed to heat or flame. Moderately explosive when exposed to flame. When heated to decomposition it emits hghly toxic fumes of phosgene and Cl-. To fight fire, use foam, COa, dry chemical. Incompatible with oxidizing materials
Purification Methods	Shake it repeatedly with conc H2SO4 (until no further colour develops in the acid), then wash it with water, aqueous NaHCO3 or Na2CO3, and more water. Dry it with CaCl2, or MgSO4 (then with P2O5 if desired), decant and fractionally distil it. Alternatively, a stream of oxygen continuing ca three times as long as is necessary to obtain the first coloration of starch iodide paper by the exit gas. After washing with NaHCO3 solution to hydrolyse ozonides and to remove the resulting organic acid, the liquid is dried and distilled [Chien & Willard J Am Chem Soc 75 6160 1953]. [Beilstein 1 IV 246.]