Adipic acid

$2.30 10000KG

$3.40 100KG

Min. Order100KG
Purity99%
Cas No124-04-9
Supply Ability200T
Update time2019-07-06

career henan chemical co

6YR

China

Chemical Properties

Product Name	Adipic acid
CAS No	124-04-9
EC-No	204-673-3
Min. Order	100KG
Purity	99%
Supply Ability	200T
Release date	2019/07/06

CR337

Product Name:	Adipic acid
Synonyms:	RARECHEM AL BO 0180;AKOS BBS-00004308;ADIPIC ACID;adipinic acid;1,6-HEXANEDIOIC ACID;1,4-BUTANEDICARBOXYLIC ACID;BUTANE-1,4-DICARBOXYLIC ACID;DICARBOXYLIC ACID C6
CAS:	124-04-9
MF:	C6H10O4
MW:	146.14
EINECS:	204-673-3
Product Categories:	Industrial/Fine Chemicals;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;Food additive and acidulant;plasticizer
Mol File:	124-04-9.mol

Adipic acid Chemical Properties

Melting point	151-154 °C(lit.)
Boiling point	265 °C100 mm Hg(lit.)
density	1,36 g/cm³
vapor density	5 (vs air)
vapor pressure	1 mm Hg ( 159.5 °C)
FEMA	2011 \| ADIPIC ACID
Fp	385 °F
storage temp.	Store below +30°C.
solubility	methanol: 0.1 g/mL, clear, colorless
pka	4.43(at 25℃)
form	Solid
color	White
PH	2.7 (23g/l, H2O, 25℃)
Water Solubility	1.44 g/100 mL (15 ºC)
Merck	14,162
BRN	1209788
Stability:	Stable. Substances to be avoided include ammonia, strong oxidizing agents.
InChIKey	WNLRTRBMVRJNCN-UHFFFAOYSA-N
CAS DataBase Reference	124-04-9(CAS DataBase Reference)
NIST Chemistry Reference	Hexanedioic acid(124-04-9)
EPA Substance Registry System	Hexanedioic acid(124-04-9)

Safety Information

Hazard Codes	Xi
Risk Statements	36-41
Safety Statements	26-39-24/25
RIDADR	UN 9077
WGK Germany	1
RTECS	AU8400000
TSCA	Yes
HS Code	29171210
Hazardous Substances Data	124-04-9(Hazardous Substances Data)

MSDS Information

Provider	Language
1,4-Butanedicarboxylic acid	English
SigmaAldrich	English
ACROS	English

Adipic acid Usage And Synthesis

As a flavor ingredient

Identification

CAS.No.:		124-04-9		FL.No.:		8.026			FEMA.No.:	2011	NAS.No.:	2011
CoE.No.:		26		EINECS.No.:		204-673-3			JECFA.No.:	623	E.No.:	E355

Description: Adipic acid is a crystalline powder with practically no odor. It has the lowest acidity of any of the acids commonly used in foods and has excellent buffering capacity in the range of pH 2.5 to 3.0. Like succinic and fumaric acid, adipic acid is practically nonhygroscopic. Its addition to foods imparts a smooth, tart taste. In grape-flavored products, it adds a lingering supplementary flavor and gives an excellent set to food powders containing gelatin. As a result, adipic acid has found a wide number of uses as an accidulant in dry powdered food mixtures, especially in those products having delicate flavors and where addition of tang to the flavor is undesirable.
Its aqueous solutions have the lowest acidity of any of the common food acids. For concentrations from 0.5 to 2.4 g/100 mL, the pH of its solution varies less than half a unit. Hence, it can be used as a buffering agent to maintain acidities within the range of 2.5 to 3.0. This is highly desirable in certain foods, yet the pH is low enough to inhibit the browning of most fruits and other foodstuffs.
Regulatory Status:
CoE: Approved
FDA: 21 CFR 131.111, 184.1009, 582.1009
FDA (other): n/a
JECFA:ADI: 0–5 mg/kg bw (1977). No safety concern when used at current levels as a flavoring agent (1999).

Reported uses (ppm): (FEMA, 1994)

Food Category	Usual	Max.
Alcoholic beverages	40	40
Baked goods	0.04	0.13
Condiments, relishes	14.01	14.09
Fats, oils	2700	2700
Gelatins, puddings	3.4	4
Gravies	0.75	1
Imitation dairy	4250	4250
Instant coffee, tea	0.01	0.04
Meat products	2.67	2.67
Nonalcoholic beverages	0.04	0.05
Poultry	0.15	0.15
Snack foods	0.5	1.86

Natural occurrence: Reported found as a minor constituent in butter, and has been found in other fats as a product of oxidative rancidity. It also occurs in beet juice, pork fat, guava fruit (Psidium guajava L.), papaya (Carica papaya L.) and raspberry (Rubus idaeus L.).

Chemical Properties

white crystalline powder

Uses

progestin

Uses

Adipic Acid is primarily used in the synthesis of nylon. It has been used as a reagent in the solid-state polymerization of nylon analogs.

Definition

ChEBI: An alpha,omega-dicarboxylic acid that is the 1,4-dicarboxy derivative of butane.

General Description

Adipic acid is a white crystalline solid. Adipic acid is insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Adipic acid is used to make plastics and foams and for other uses.

Air & Water Reactions

Dust may form explosive mixture with air [USCG, 1999]. Insoluble in water.

Reactivity Profile

Adipic acid is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Adipic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions. Behavior in Fire: Melts and may decompose to give volatile acidic vapors of valeric acid and other substances.

Health Hazard

Inhalation of vapor irritates mucous membranes of the nose and lungs, causing coughing and sneezing. Contact with liquid irritates eyes and has a pronounced drying effect on the skin; may produce dermatitis.

Fire Hazard

Behavior in Fire: Melts and may decompose to give volatile acidic vapors of valeric acid and other substances. Dust may form explosive mixture with air.

Adipic acid Preparation Products And Raw materials

Preparation Products

Cyclopentanone-->Polyurethane foams-->1,5-Pentanedioic acid-->Triethylene glycol dimethacrylate-->1,6-HEXANEDIAMINE-->1,6-Diisocyanatohexane-->Glutaric anhydride-->LIGNOCERIC ACID-->Fluorescent Brightener 184-->Monostearin-->Cyclopentanol-->1,4-Dicyanobutane-->PolyesterPolyol-->2,5-Thiophenedicarboxylic acid-->Diethyl adipate-->2,2-DIMETHYLCYCLOPENTANONE-->Adipoyl chloride-->NYLON 6-->polyesters containing quarternary ammonium groups-->NYLON 6/6-->Dioctyl adipate-->Water-soluble resin-->Diethyl 2,5-dibromohexanedioate-->Dibutyl adipate -->Bis(2-ethylhexyl) adipate-->Dimethyl adipate-->Monoethyl Adipate

Raw materials

Sodium hydroxide-->Nitric acid-->Copper-->Cyclohexane-->Cyclohexanone-->1,3-BUTADIENE-->Cupric acetate monohydrate -->Cyclohexanol-->Vanadium pentoxide -->Cyclohexene-->Bromide-->MANGANESE(II) ACETATE-->METABORIC ACID