1. Product information
Product Name: | 1,5-Dihydroxy naphthalene |
Synonyms: | Naphthalene-1,5-diol;1,8-NAPHTHALENEDIMETHANOL;1,5-DIHYDROXYNAPHTHALENE;1,5-NAPHTHALENEDIOL;1,5-Dihydroxynaphthalene 97%;1,5-Dihydroxy phthalene;1,5-Naphthalenediol for synthesis;1,5-DihydroxynaphthaL |
CAS: | 83-56-7 |
MF: | C10H8O2 |
MW: | 160.17 |
EINECS: | 201-487-4 |
Product Categories: | Intermediates of Dyes and Pigments;Naphthalene derivatives;Indazoles;bc0001 |
Mol File: | 83-56-7.mol |
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1,5-Dihydroxy naphthalene Chemical Properties |
Melting point | 259-261 °C (dec.) (lit.) |
Boiling point | 246.06°C (rough estimate) |
density | 1.0924 (rough estimate) |
vapor pressure | 0-0Pa at 25℃ |
refractive index | 1.5418 (estimate) |
Fp | 252°C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | 0.6g/l |
pka | 9.28±0.40(Predicted) |
form | Solid |
color | Pale Beige to Very Dark Brown |
PH | 6 (0.5g/l, H2O, 20℃) |
Water Solubility | Soluble in water. |
1,5-Dihydroxy naphthalene Usage And Synthesis |
Chemical Properties | Grey powder 1,5-Naphthalenediol [83-56-7], 1,5-dihydroxynaphthalene, Azurol, C10H8O2, Mr 160.16, forms colorless needles (from aqueous methyl cellosolve). The compound is sublimable, readily soluble in ether and acetone, but only sparingly soluble in water and hydrocarbons. It is oxidized to 5-hydroxy-1,4-naphthoquinone ( juglone) by CrO3. Amination gives 1,5-naphthalenediamine; coupling with diazotized anilines occurs in the 2- or 4-position. |
Uses | 1,5-Dihydroxynaphthalene is an intermediate of synthetic mordant azo dyes. It is an intermediate used in organic synthesis, pharmaceuticals, dyestuff fields and photograph industry. It is used as a coupling component in azo dyes as exemplified in the metallizable (Cr) wool dye, C.I. Mordant Black 9. |
Production Methods | The sodium salt of naphthalene-1,5-disulfonic acid is added gradually to excess 75 % sodium hydroxide. The mixture is heated under pressure to 276℃ over the course of 7 h and the reaction is completed by heating for a further 5 h at this temperature. After precipitation with sulfuric acid, the product is isolated in 90 % yield. |
2. Packaging
For powders: normal is 25kgs/Drum or bag, or larger/smaller package as request.
For liquids: normal 25kgs/drum, 180-300kgs/bucket, or IBC, determined by the nature of the product.
Or smaller package 1kg/bottle, 10kgs/bottle as request.
3. Shipping
4. Contact information
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