Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3

$0.00 10g

$0.00 100g

$0.00 1000g

Min. Order1g
Purity0.98
Cas No1536473-72-9
Supply Ability50KG
Update time2021-06-11

Wuhan LPBchem Technology Co.,Ltd

5YR

China

Since2018-11-29

AddressNO.390, HIGH-TECH ROAD, HONGSHAN DISTRICT, WUHAN, HUBEI, CHINA

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Chemical Properties

Product Name	Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3
CAS No	1536473-72-9
EC-No
Min. Order	1g
Purity	0.98
Supply Ability	50KG
Release date	2021/06/11

1536473-72-9

tBuBrettPhos PdG3

Synonym: tert-BuBrettPhos-Pd-G3,

[(2-Di-tert-butylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

CAS Number: 1536473-72-9

Formula: C44H62NO5PPdS

Formula Weight: 854,43 g/mol

Appearance (Color) White to Very Dark Green to Very Dark

assay 98%

mp 119-131 °C

Caution : air sensitive

shelf life :12 month

Supplier: LPBchem-Benjamin

ISO9001 Manufacturer

Standard laboratory

ligands catalysts synthesis pharmaceutical compounds electronic intermediates

Related Categories

Buchwald 3rd Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,

Homogeneous Pd Catalysts, Palladium Catalysts

General description

tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate

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Company Profile Introduction

Wuhan LPBchem Technology Co., Ltd, we produce over 50 kinds of palladium catalysts for custom synthesis, especially for the pharmaceutical researching industry. We are a ISO9001:2005 proved manufacturer, owning a lab more than 1500 squaremeters, consistent of PhD from Top University with many years of experience in China, supplying small to large custom synthesis customers and pharmacy companies, and also exporters around the world with direct bottom quotation and guaranteed quality. We aimed to help customer's synthesis process, and are glad to create value with customers together. Email: Benjamin@LPBchem.com WhatsApp:+86-15071314134 Www.LPBchem.com Tel : +86-027-693498399