1. Product information
| Product Name: | 1-Iodo-3,5-dimethylbenzene |
| Synonyms: | 3,5-dimethylphenyl iodide;1,3-DIMETHYL-5-IODOBENZENE;1-IODO-3,5-DIMETHYLBENZENE;3,5-DIMETHYLIODOBENZENE;5-IODO-M-XYLENE;5-Iodo-m-xylene (stabilized with Copper chip);5-Iodo-m-xylene,99%;Benzene, 1-Iodo-3,5-dimethyl- |
| CAS: | 22445-41-6 |
| MF: | C8H9I |
| MW: | 232.06 |
| EINECS: | 629-121-2 |
| Product Categories: | Aromatic Hydrocarbons (substituted) & Derivatives;Halogen toluene;Iodine Compounds |
| Mol File: | 22445-41-6.mol |
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| 1-Iodo-3,5-dimethylbenzene Chemical Properties |
| Melting point | -2.9°C (estimate) |
| Boiling point | 92-94 °C3 mm Hg(lit.) |
| density | 1.608 g/mL at 25 °C(lit.) |
| refractive index | n20/D 1.594(lit.) |
| Fp | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Sparingly soluble (0.014 g/L) (25°C), Calc. |
| form | Liquid |
| Specific Gravity | 1.608 |
| color | Clear light yellow |
| Sensitive | Light Sensitive |
| 1-Iodo-3,5-dimethylbenzene Usage And Synthesis |
| Chemical Properties | clear light yellow liquid |
| Uses | suzuki reaction |
| Uses | 1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethyl aniline, an aryl amine, It is also used in the following studies; α-Arylation of ketones, Copper-catalyzed N-arylation of imidazoles, Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile, synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol, CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine, copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. It is also employed as a starting material in the synthesis of biphenyl-3,3?,5,5?-tetracarboxylic acid, radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene. |
| Uses | 1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethylaniline, an arylamine.
It may be used in the following studies:
α-Arylation of ketones. Copper-catalyzed N-arylation of imidazoles. Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile. Synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol. CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine. Copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. As a starting material in the synthesis of biphenyl-3,3′,5,5′-tetracarboxylic acid. Radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.
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| General Description | 1-Iodo-3,5-dimethylbenzene (5-Iodo-m-xylene) is an aryl halide. It can be obtained from 5-bromo-m-xylene, via copper-catalyzed halogen exchange reaction, in the presence of NaI or KI in n-BuOH or DMF (solvents). It undergoes reaction with phenol in the presence of CuFe2O4 nano powder as a recyclable catalyst to afford 1,3-dimethyl-5-phenoxybenzene. |
2. Packaging
For powders: normal is 25kgs/Drum or bag, or larger/smaller package as request.
For liquids: normal 25kgs/drum, 180-300kgs/bucket, or IBC, determined by the nature of the product.
Or smaller package 1kg/bottle, 10kgs/bottle as request.
3. Shipping
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