IHIC, also known as 4TIC, has an acceptor–donor–acceptor (A–D–A) structure consisting of an electron-rich fused hexacyclic unit dithienocyclopentathieno[3,2-b]thiophene core and two electron withdrawing 1,1-dicyanomethylene-3-indanone (IC) terminal units. The rigid planar structure of dithienocyclopentathieno[3,2-b]thiophene promotes inter-molecular charge transport.