Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)

Product NameChloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
CAS1353658-81-7
MFC30H42ClNPPd+2
MW589.507941
EINECS
MOL File1353658-81-7.mol

Chemical Properties

Melting point	244-246 °C
form	solid

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26

Usage And Synthesis

Uses

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:

To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
In the C-H bond functionalization reactions.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: C-H Activation
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings