トリフルオロ酢酸

￥1700 - ￥293000

化学名トリフルオロ酢酸

英語名Trifluoroacetic acid

CAS番号76-05-1

分子式C2HF3O2

分子量114.02

EINECS200-929-3

MDL NumberMFCD00004169

别名

トリフルオロ酢酸

トリフルオロ酢酸 (約0.5mol/L水溶液) [イオン対試薬]

(トリフルオロ酢酸)アニオン

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価格 118 物価

ブランド less more

富士フイルム和光純薬株式会社(wako) 東京化成工業関東化学株式会社(KANTO) Sigma-Aldrich Japan ナカライテスク株式会社(Nacalai) キシダ化学株式会社(Kishida) 林純薬工業株式会社純正化学株式会社
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1ml 2ml 5x1ml 5ml 1ml×10 5x1.5ml 4x2ml (1ml×10)×10 10x1ml 10ml 5ml×10 5x3ml 25g (1ml×10)×5 25ml 50g 5ml×5a 40ml 50ml 100ml 100g 250g 250ml 4x100ml 450ml 500g 500ml 1kg 2.5kg 5kg 1ml×5 1l 1pack 1ml-f 3ml×5a 1amp 1ml×5a 5ml-f 10ml-f 10amp 5x10amp 10x10amp

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生産者	包装単位	価格	製品説明
富士フイルム和光純薬株式会社(wako) W01W0120-0274	25mL	￥1870	トリフルオロ酢酸 Trifluoroacetic Acid
富士フイルム和光純薬株式会社(wako) W01W0120-0274	100mL	￥5650	トリフルオロ酢酸 Trifluoroacetic Acid
富士フイルム和光純薬株式会社(wako) W01W0120-0639	1mL×5	￥6350	トリフルオロ酢酸 Trifluoroacetic Acid
富士フイルム和光純薬株式会社(wako) W01FLC001271	250g	￥8100	トリフルオロ酢酸 Trifluoroacetic acid
富士フイルム和光純薬株式会社(wako) W01W0120-1078	40mL	￥8450	25%トリフルオロ酢酸溶液 25% Trifluoroacetic Acid Solution
富士フイルム和光純薬株式会社(wako) W01APOPC7160	250g	￥9100	トリフルオロ酢酸 Trifluoroacetic acid
富士フイルム和光純薬株式会社(wako) W01APOPC7160A	1L	￥30700	トリフルオロ酢酸 Trifluoroacetic acid
富士フイルム和光純薬株式会社(wako) W01W0120-1073	5mL×5A	￥37400	トリフルオロ酢酸 Trifluoroacetic Acid
富士フイルム和光純薬株式会社(wako) W01APOPC7160	2.5kg	￥45600	トリフルオロ酢酸 Trifluoroacetic acid
富士フイルム和光純薬株式会社(wako) W01FLC001271	2.5kg	￥50000	トリフルオロ酢酸 Trifluoroacetic acid

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プロパティ

融点	-15.4 °C (lit.)
沸点	72.4 °C (lit.)
比重(密度)	1.489 g/mL at 20 °C (lit.)
蒸気密度	3.9 (vs air)
蒸気圧	97.5 mm Hg ( 20 °C)
屈折率	n20/D 1.3(lit.)
闪点	None
貯蔵温度	Store at +15°C to +25°C.
溶解性	Miscible with ether, acetone, ethanol, benzene, hexane, and CCl<sub>4</sub>
酸解離定数(Pka)	-0.3(at 25℃)
外見	Liquid
比重	1.480
色	Colorless
PH	1 (10g/l, H2O)
酸塩基指示薬変色域(pH)	1
臭い (Odor)	Sharp, pungent odor
水溶解度	miscible
Sensitive	Hygroscopic
極大吸収波長 (λmax)	λ: 260 nm Amax: 0.9 λ: 270 nm Amax: 0.10 λ: 280 nm Amax: 0.05 λ: 290 nm Amax: 0.04 λ: 300 nm Amax: 0.03 λ: 320 nm Amax: 0.025
Merck	14,9681
BRN	742035
Dielectric constant	23.7（20℃）
安定性：	Stable. Incompatible with combustible material, strong bases, water, strong oxidizing agents. Non-combustible. Hygroscopic. May react violently with bases.
InChIKey	DTQVDTLACAAQTR-UHFFFAOYSA-N
CAS データベース	76-05-1(CAS DataBase Reference)
NISTの化学物質情報	Acetic acid, trifluoro-(76-05-1)
EPAの化学物質情報	Acetic acid, 2,2,2-trifluoro- (76-05-1)

安全情報

説明

Trifluoroacetic acid (TFA, molecular formula: CF3COOH) is a kind of colorless, volatile and fuming liquid with a similar odor as acetic acid. It is hygroscopic and has irritating odor. It has strong acidic property due to being affected by the electron-attracting trifluoromethyl group with its acidicity being 100000 higher than acetic acid. It has a melting point being-15.2 ℃, boiling point being 72.4 ℃, and the density being 1.5351g/cm3 (1℃). It is miscible with water, fluorinated hydrocarbons, methanol, ethanol, ethyl ether, acetone, benzene, carbon tetrachloride, and hexane; it is partially soluble in carbon disulfide and alkane containing more than six carbons. It is an excellent solvent of protein and polyester. It is also a good solvent for the organic reaction which allows obtaining certain results which are difficult in the cases of application of common solvents. For example, when quinolone is being catalyzed for hydrogenation in a common solvent, the pyridine ring is preferentially hydrogenated; in contrast, the benzene ring will be preferentially hydrogenated in the presence of trifluoroacetic acid as the solvent. Trifluoroacetic acid is decomposed into carbon dioxide and fluorine in the presence of aniline. It can be reduced by sodium borohydride or lithium aluminum hydride into trifluoroacetic acetaldehyde and trifluoro-ethanol. It is stable at temperature higher than 205 ℃ stable. But its ester and amides derivatives are easily subject to hydrolysis which allows them to prepare carbohydrate, amino acids, and peptide derivative in the form of acid or anhydride. It is easily to be dehydrated under action of phosphorus pentoxide and be converted to trifluoroacetic anhydride.
Trifluoroacetic acid is a kind of important intermediates of fat fluorine. Owing to the special structure of trifluoromethyl, it has a different property from other alcohols and can participate in a variety of organic reactions, especially being used in the field of the synthesis of fluorine-containing pharmaceutical, pesticides and dyes. Its domestic and foreign demand is increasing and has become one of the important intermediates for fluorine-containing fine chemicals.

トリフルオロ酢酸

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