BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

Safety Information

Symbol(GHS)

Signal word

Warning

Hazard statements

H227：Combustible liquid

H315：Causes skin irritation

H319：Causes serious eye irritation

Precautionary statements

P210：Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264：Wash hands thoroughly after handling.

P264：Wash skin thouroughly after handling.

P280：Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235：Store in a well-ventilated place. Keep cool.

P501：Dispose of contents/container to..…

Description

Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.
The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.

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Suppliers and manufacturers

• Career Henan Chemica Co
• Dayang Chem (Hangzhou) Co.,Ltd.
• Zhejiang J&C Biological Technology Co.,Limited
• Alfa Chemistry
• PT CHEM GROUP LIMITED
• GIHI CHEMICALS CO.,LIMITED
• Aladdin Scientific
• Guangzhou CATO Research Chemicals Inc.
• J & K SCIENTIFIC LTD.
• Meryer (Shanghai) Chemical Technology Co., Ltd.

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