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(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
$54 - $2246
Product name
(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
Cas No
136735-95-0
MF
C18H28P2
MW
306.36
MDL Number
MFCD00142322
Synonyms
(+)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)benzene (S,S)-Me-DUPHOS;(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene kanata purity;(S,S)-METHYL-DUPHOS;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene,98+%(S,S)-Me-DUPHOS;(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE;(2S,2'S,5S,5'S)-2,2',5,5'-TETRAMETHYL-1,1'-(1,2-PHENYLENE)DIPHOSPHOLANE;(2S,2'S,5S,5'S)-2,2',5,5'-TETRAMETHYL-1,1'-(O-PHENYLENE)DIPHOSPHOLANE;(+)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene,(2S,2′S,5S,5′S)-2,2′,5,5′-Tetramethyl-1,1′-(o-phenylene)diphospholane, (S,S)-Me-DUPHOS, (S,S)-Methyl-DUPHOS
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aablocks
Strem Chemicals
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ACHEMBLOCK
Activate Scientific
Crysdot
Alichem
American Custom Chemicals Corporation
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Product name
aablocks
AA003B95
100mg
$56
1,2-Bis((2S,5S)-2,5-dimethylphospholan-1-yl)benzene
aablocks
AA003B95
250mg
$132
1,2-Bis((2S,5S)-2,5-dimethylphospholan-1-yl)benzene
aablocks
AA003B95
1g
$452
1,2-Bis((2S,5S)-2,5-dimethylphospholan-1-yl)benzene
aablocks
AA003B95
5g
$2246
1,2-Bis((2S,5S)-2,5-dimethylphospholan-1-yl)benzene
ACHEMBLOCK
X196445
5G
$1590
(S,S)-Me-DUPHOS
ACHEMBLOCK
X196445
5G
$1590
(S,S)-Me-DUPHOS
ACHEMBLOCK
X196445
250MG
$115
(S,S)-Me-DUPHOS
ACHEMBLOCK
X196445
250MG
$115
(S,S)-Me-DUPHOS
ACHEMBLOCK
X196445
1G
$320
(S,S)-Me-DUPHOS
ACHEMBLOCK
X196445
1G
$320
(S,S)-Me-DUPHOS
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Properties
Melting point
67-76 °C
alpha
D25 +476± 5° (c = 1 in hexane)
Boiling point
415.0±15.0 °C(Predicted)
storage temp.
under inert gas (nitrogen or Argon) at 2-8°C
form
crystal
color
white
Water Solubility
Insoluble in water.
Sensitive
Air Sensitive
BRN
4810602
InChI
InChI=1S/C18H28P2/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m0/s1
InChIKey
AJNZWRKTWQLAJK-VGWMRTNUSA-N
SMILES
C1(P2[C@@H](C)CC[C@@H]2C)=CC=CC=C1P1[C@@H](C)CC[C@@H]1C
Safety Information
Symbol(GHS)
Signal word
Warning
Hazard statements
H302:
Harmful if swallowed
Precautionary statements
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
Description
It is a DuPhos and BPE ligands which are highly efficient privileged ligands.
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