수소화칼륨

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Danger

• 유해·위험 문구

  H260：물과 접촉시 자연 발화성 인화성 가스를 발생시킴

  H314：피부에 심한 화상과 눈에 손상을 일으킴

• 예방조치문구

  P223：물과 접촉하지 마시오.

  P231+P232：불활성 기체 하에서 취급하고, 습기를 방지하시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P303+P361+P353：피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.

  P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

수소화칼륨 화학적 특성, 용도, 생산

• 화학적 성질

  Potassium hydride is available in laboratory quantities only as a 20 – 35 % dispersion in oil. Potassium hydride is a considerably stronger base than lithium hydride or sodium hydride. It is able to remove protons from tertiary alcohols and ketones, a reaction that either does not occur or is very slow when sodium hydride is used. Potassium hydride also reacts with weak Lewis acids, converting sterically hindered boron trialkyls to the corresponding sterically hindered complex borohydrides:
  

• 용도

  Potassium Hydride is used in preparation of Hydroxy-Xanthone derivatives via Isoprenylation followed by Claisen rearrangement starting from Fluoroxanthone derivatives.

• 정의

  potassium hydride: A white orgreyish white crystalline solid, KH;r.d. 1.43–1.47. It is prepared by passinghydrogen over heated potassiumand marketed as a light grey powderdispersed in oil. The solid decomposeson heating and in contact withmoisture and is an excellent reducingagent. Potassium hydride is a firehazard because it produces hydrogenon reaction with water.

• 화학 반응

  Potassium hydride acts as a base and as hydride donor. It is used for deprotonation, cyclization-condensation, elimination, and rearrangement reactions, and also as a reducing agent. Potassium hydride undergoes reaction quickly and quantitatively with acids, and of particular note is its capability to rapidly deprotonate tertiary alcohols where sodium hydride or potassium metal do so slowly or not at all. The reactions of metal hydrides take place at the crystal surface. The crystal lattice energies decrease from lithium to cesium hydride, and potassium hydride appears to have the optimal lattice energy and hydride radius for surface reactions. The presence of 18-crown-6 enhances the reactivity of potassium hydride, The crown ether can operate as a phase-transfer agent or as a simple “pickling” agent of the potassium hydride surface, dissolving the formed inorganic salts. Potassium hydride is usually superior to lithium and sodium hydride in the reactions. Unusually active potassium hydride can be prepared easily from hydrogen and superbasic reagents (t-BuOK-TMEDA) in hexane. “Superactive potassium hydride” is very active in deprotonation as well as in reduction. The reactivity of commercially available potassium hydride, which is prepared by the reaction of hydrogen gas with elemental potassium, depends upon the impurities in different lots (mainly potassium or its reaction products), thus leading to side reactions and variable yields. The superactive metal hydride contains no alkali metal.

• 일반 설명

  This product has been enhanced for energy efficiency.

• 위험도

  Dangerous fire and explosion risk, evolves toxic and flammable gases on heating and on expo- sure to moisture.

• 건강위험

  Potassium hydride react with the moisture on skin and other tissues to form highly corrosive sodium and potassium hydroxide. Contact of these hydrides with the skin, eyes, or mucous membranes causes severe burns; thermal burns may also occur due to ignition of the liberated hydrogen gas.

• 화재위험

  Potassium hydride is flammable solid that ignite on contact with moist air. Potassium hydride presents a more serious fire hazard than sodium hydride. The mineral oil dispersions do not ignite spontaneously on exposure to the atmosphere. Sodium hydride and potassium hydride fires must be extinguished with a class D dry chemical extinguisher or by the use of sand, ground limestone, dry clay or graphite, or "Met-L-X ? " type solids. Water or CO 2 extinguishers must never be used on sodium and potassium hydride fires.

• 인화성 및 폭발성

  Potassium hydride and sodium hydride are flammable solids that ignite on contact with moist air. Potassium hydride presents a more serious fire hazard than sodium hydride. The mineral oil dispersions do not ignite spontaneously on exposure to the atmosphere. Sodium hydride and potassium hydride fires must be extinguished with a class D dry chemical extinguisher or by the use of sand, ground limestone, dry clay or graphite, or "Met-L-X?" type solids. Water or CO2 extinguishers must never be used on sodium and potassium hydride fires.

• Safety Profile

  Dangerous fire hazard by chemical reaction. Ignites spontaneously in air. Moderate explosion hazard when exposed to heat or by chemical reaction. Wdl react with water, steam, or acids to produce H2 which then igmtes. Can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical. Potentially explosive reactions with 0-2,4- dnitrophenylhydroxylamine, fluoroalkenes. Ignites on contact with air, oxygen + moisture, fluorine. Incompatible with Cl2, acetic acid, acrolein, acrylonitrile, (CaC + Cl2), ClO2, (H202 + Cl2), (CHFL + CH,OH), 1,2-dchloroethylene, maleic anhydride, (n-methyl-n-nitrosourea + CH2Cl2), nitroethane, NCb, nitromethane, nitroparaffins, o-nitrophenol, nitropropane, n-nitrosomethylurea, (nitrosomethylurea + CH2Cl2), H20, trichloroethylene, tetrahydrofuran, tetrachlorethane. When heated to decomposition it emits highly toxic fumes of K2O. See also POTASSIUM and HYDRIDES.

• 저장

  Safety glasses, impermeable gloves, and a fire-retardant laboratory coat should be worn at all times when working with these substances. These hydrides should be used only in areas free of ignition sources and should be stored preferably as mineral oil dispersions under an inert gas such as argon.

• 비 호환성

  Potassium hydride and sodium hydride react violently with water, liberating hydrogen, which can ignite. Oil dispersions of these hydrides are much safer to handle because the mineral oil serves as a barrier to moisture and air. Potassium hydride may react violently with oxygen, CO, dimethyl sulfoxide, alcohols, and acids. Explosions can result from contact of these compounds with strong oxidizers. Potassium hydride is generally more reactive than sodium hydride.

• 폐기물 처리

  Excess potassium or sodium hydride and waste material containing these substances should be placed in an appropriate container under an inert atmosphere, clearly labeled, and handled according to your institution's waste disposal guidelines. Experienced personnel can destroy small quantities of sodium hydride and potassium hydride by the careful dropwise addition of t-butanol or iso-propanol to a suspension of the metal hydride in an inert solvent such as toluene under an inert atmosphere such as argon. Great care must be taken in the destruction of potassium hydride because of its greater reactivity. The resulting mixture of metal alkoxide should be placed in an appropriate container, clearly labeled, and handled according to your institution's waste disposal guidelines.

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