리나롤

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Warning

• 유해·위험 문구

  H315：피부에 자극을 일으킴

  H317：알레르기성 피부 반응을 일으킬 수 있음

  H319：눈에 심한 자극을 일으킴

• 예방조치문구

  P261：분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.

  P264：취급 후에는 손을 철저히 씻으시오.

  P264：취급 후에는 손을 철저히 씻으시오.

  P272：작업장 밖으로 오염된 의복을 반출하지 마시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P302+P352：피부에 묻으면 다량의 물로 씻으시오.

  P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

리나롤 MSDS

• 3,7-Dimethyl-1,6-octadien-3-ol

리나롤 화학적 특성, 용도, 생산

• 용도

  품목은 무색투명한 액체로서 특이한 향기가 있다.

• 용도

  그것은 합성 풍미와 향수 공업 (FEMA 2635)에서 통용되고 또한 isophytol, VE 및 VK의 종합을 위한 원료입니다.

• 순도시험

    (1) 비중 : 이 품목의 비중은 0.858～0.867이어야 한다.

    (2) 굴절률 : 이 품목의 굴절률 은 1.461～1.465이어야 한다.

    (3) 용상 : 이 품목 1mL를 60% 에탄올 4mL에 녹일 때, 그 액은 징명하여야 한다.

    (4) 염소화합물 : 이 품목은 향료시험법 중 할로겐시험법의 동망법에 따라 시험을 할 때, 이에 적합하여야 한다.

    (5) 산가 : 이 품목의 산가는 향료시험법 중 산가측정법에 따라 시험할 때, 1 이하이어야 한다.

    (6) 에스테르가 : 이 품목 약 5g을 정밀히 달아 향료시험법 중 에스테르가 및 에스테르함량측정법에 따라 시험할 때, 2 이하이어야 한다.

• 확인시험

    이 품목 1mL에 무수초산 1mL 및 인산 1방울을 넣고 10분간 미온에 방치한 다음 물 1mL를 넣어 온탕 중에서 5분간 흔들어 섞고 이 액을 식힌 다음 탄산나트륨시액으로 약알칼리성화하면 초산나트륨 향기를 발생한다.

• 정량법

    이 품목 10mL를 플라스크에 넣고 얼음 중에서 10분간 방치한 다음 디메틸아닐린 20mL를 넣어 잘 흔들어 섞는다. 이에 염화아세틸(리나롤 정량용) 10mL 및 무수초산 5mL를 넣고 공기냉각기를 달아 잘 흔들어 섞으면서 냉수에서 5분간 방치하고 다시 실온에서 30분간 방치한 다음 50℃의 수욕 중에서 4시간 가열한다. 이를 식힌 다음 내용물을 분액깔대기에 옮겨서 얼음물 75mL씩을 사용하여 3회 씻는다. 다시 기름층을 묽은황산 25mL씩으로 씻어서 씻은 액에 수산화나트륨시액을 넣고 알칼리성으로 할 때, 탁하지 않을 때까지 반복한 다음 탄산나트륨시액 10mL씩으로 씻어 씻은 액이 알칼리성으로 될 때까지 반복한다. 다시 염화나트륨 25mL씩으로 씻은 액이 중성으로 될 때까지 씻은 다음 기름층을 건조된 플라스크에 옮기고 무수황산나트륨 2g을 넣고 잘 흔들어 섞어 30분간 방치한 다음 여과한다. 이 여액 약 1g을 정밀히 달아 향료시험법 중 에스테르가 및 에스테르함량측정법에 따라 시험한다. 따로 같은 방법으로 공시험을 한다.

          a : 공시험의 0.5N 염산의 소비량(mL)

          b : 본시험의 0.5N 염산의 소비량(mL)

          s : 여액의 채취량(g)

• 개요

  Linalool has a typical floral odor free from camphoraceous and terpenic notes.1 Synthetic linalool exhibits a cleaner and fresher note than the natural product. It can be prepared synthetically starting from myrcene or from dehydrolinalool.
  The optically active forms (d- and ι-) and the optically inactive form occur naturally in more than 2 0 0 oils from herbs, leaves, flowers, and wood; the ι-form is present in the largest amounts (80 - 85%) in the distillates from leaves of Cinnamomum cam phora var. orientalis and Cinnamomum camphora var. occidentalis and in the distillate from Cajenne rosewood; it also has been reported in: champaca, ylang-ylang, neroli, Mexican linaloe, ber gamot, lavandin, and others; a mixture of d- and ι-linalool has been reported in Brazil rosewood (85%); the d-form has been found in palmarosa, mace, sweet orange-flower distillate, petit grain, coriander (60 - 70%), marjoram, Orthodon linalooliferum (80%), and others; the inactive form has been reported in clary sage, jasmine, and Nectandra elaiophora.

• 화학적 성질

  Linalool occurs as one of its enantiomers in many essential oils, where it is often the main component. (3R)- (?)-Linalool, for example, occurs at a concentration of 80–85% in Ho oils from Cinnamomum camphora; rosewood oil contains about 80%. (3S)-(+)- Linalool makes up 60–70% of coriander oil (“coriandrol”).
  Linalool is used frequently in perfumery for fruity notes and for many floral fragrance compositions (lily of the valley, lavender, and neroli). Because of its relatively high volatility, it imparts naturalness to top notes. Since linalool is stable in alkali, it can be used in soaps and detergents. Linalyl esters can be prepared from linalool.Most of the manufactured linalool is used in the production of vitamin E.

• 물리적 성질

  Properties. Racemic linalool is, similarly to the individual enantiomers, a colorless liquid with a floral, fresh odor, reminiscent of lily of the valley. However, the enantiomers differ slightly in odor. Together with its esters, linalool is one of the most frequently used fragrance substances and is produced in large quantities. In the presence of acids, linalool isomerizes readily to geraniol, nerol, and α-terpineol. It is oxidized to citral, for example, by chromic acid. Oxidation with peracetic acid yields linalool oxides, which occur in small amounts in essential oils and are also used in perfumery. Hydrogenation of linalool gives tetrahydrolinalool, a stable fragrance material. Its odor is not as strong as, but is fresher than, that of linalool. Linalool can be converted into linalyl acetate by reaction with ketene or with an excess of boiling acetic anhydride.

• 출처

  The optically active forms (d- and l-) and the optically inactive form occur naturally in more than 200 oils from herbs, leaves, flowers and wood; the l-form is present in the largest amounts (80 to 85%) in the distillates from leaves of Cinnamomum camphora var. orientalis and Cinnamomum camphora var. occidentalis and in the distillate from Cajenne rosewood; it also has been reported in champaca, ylang-ylang, neroli, Mexican linaloe, bergamot and lavandin; a mixture of d- and l-linalool has been reported in Brazil rosewood (85%); the d-form has been found in palmarosa, mace, sweet orange-flower distillate, petitgrain, coriander (60 to 70%), marjoram and Orthodon linalooliferum (80%); the inactive form has been reported in clary sage, jasmine and Nectandra elaiophora. Also reported found in over 280 products including apple, citrus peel oils and juices, berries, grapes, guava, celery, peas, potato, tomato, cinnamon, cloves, cassia, cumin, ginger, mentha oils, mustard, nutmeg, pepper, thymus, cheeses, grape wines, butter, milk, rum, cider, tea, passion fruit, olive, mango, beans, coriander, cardamom and rice.

• 용도

  linalool is a fragrant component of both lavender and coriander. It can be incorporated into cosmetics for perfuming, deodorant, or odor-masking activity.

• 정의

  ChEBI: A monoterpenoid that is octa-1,6-diene substituted by methyl groups at positions 3 and 7 and a hydroxy group at position 3. It has been isolated from plants like Ocimum canum.

• 일반 설명

  Linalool is a monoterepene compound. It is the major component of many essential oils. Anti-inflammatory properties of (?) linalool, a naturally occurring enantiomer, has been studied. It is also the major constituent of the basil and thyme essential oil and its anti-microbial effect was determined using the agar well diffusion assay. Linalool is reported to have dose-dependent marked sedative effects at the central nervous system (CNS), including hypnotic, anticonvulsant and hypothermic properties. Linalool is reported to have a lemon like odor.

• 색상 색인 번호

  Linalool is a terpene chief constituent of linaloe oil,also found in oils of Ceylon cinnamon, sassafras,orange flower, bergamot, Artemisia balchanorum, ylang-ylang. This frequently used scented substance is a sensitizer by the way of primary or secondary oxida-tion products. As a fragrance allergen, linalool has to be mentioned by name in cosmetics within the EU

• Anticancer Research

  Studies of antitumor activities and toxicity were done on solid S-180 tumor-bearingSwiss albino mice. It results in an induction of oxidative stress with an antitumoractivities result. In comparison with cyclophosphamide, antioxidant effects wereobserved in the liver and modulation of proliferation of spleen cells in tumor-bearingmice challenged with lipopolysaccharides, while both were seriously affected bycyclophosphamide (Costa et al. 2015).

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