D-포도당 6-인산염 모노나트륨

한글명:D-포도당 6-인산염 모노나트륨

카스 번호54010-71-8

상품명:ROBISON ESTER MONOSODIUM SALT

CBNumberCB3681824

분자식C6H14NaO9P

포뮬러 무게284.13

MOL 파일54010-71-8.mol

동의어(한글)

D-포도당6-인산염모노나트륨

D-포도당6-인산염모노나트륨(D-GLUCOSE6-PHOSPHATEMONOSODIUM)

화학적 성질

녹는점	204 °C (dec.)(lit.)
저장 조건	Sealed in dry,Room Temperature
용해도	H₂O: 50 mg/mL, 투명, 무색에서 매우 희미한 노란색
물리적 상태	수정 같은
BRN	5787568
InChI	InChI=1/C6H13O9P.Na.H/c7-1-3(8)5(10)6(11)4(9)2-15-16(12,13)14;;/h1,3-6,8-11H,2H2,(H2,12,13,14);;/t3-,4+,5+,6+;;/s3
InChIKey	RUFPTDNHMAGVMV-IWNCBHIWNA-N
SMILES	[C@@H](O)([C@H](O)COP(O)(O)=O)[C@H](O)[C@@H](O)C=O.[NaH] \|&1:0,2,10,12,r\|
CAS 데이터베이스	54010-71-8(CAS DataBase Reference)

위험 및 안전 성명

위험품 표기	Xi
위험 카페고리 넘버	36/37/38
안전지침서	26-36-24/25
WGK 독일	3
F 고인화성물질	3-10
HS 번호	29400000

그림문자(GHS)

D-포도당 6-인산염 모노나트륨 화학적 특성, 용도, 생산

개요
D-Glucose-6-phosphate is formed in cells when glucose is phosphorylated by hexokinase (or glucokinase) or by the conversion of glucose-1-phosphate by phosphoglucomutase, which is the first step of glycogen synthesis. It is stored as glycogen when blood glucose levels are high. Disruption of D-glucose-6-phosphate activity leads to glycogen storage disease type I or von Gierke’s disease, a group of inherited metabolic diseases characterized by severe hypoglycemia, growth retardation, and hepatomegaly, due to accumulation of glycogen and fat in the liver. D-Glucose-6-phosphate is also the starting molecule of both glycolysis and the pentose phosphate pathways. Because cancer cells adopt glycolysis as a major source of metabolic energy production, and the pentose phosphate pathway plays a role in helping glycolytic cancer cells to meet their anabolic demands, this compound can be used to study the progression of this process.
화학적 성질
White crystalline solid
일반 설명
A glycolytic intermediate that also acts as a competitive and reversible inhibitor of hexokinase. Useful in creating an ATP-regenerating system. Causes the release of mitochondrially bound hexokinase in muscle.
Purification Methods
It can be freed from metal impurities as described for glucose-1-phosphate. The solubility of the Na salt is 5% in H2O at 20o. Its barium salt can be purified by solution in dilute HCl and precipitation by neutralising the solution. The precipitate is washed with small volumes of cold water and dried in air. Alternatively the barium salt is dissolved in H2O, 4volumes of EtOH are added, the precipitate is collected, washed with 90% EtOH, absolute EtOH, 75% EtOH/25% Et2O, 25% EtOH/75% Et2O and finally dry Et2O. The dry Barium salt has [] D +17.9o (c 1, H2O). [Beilstein 1 IV.]

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