CHLORETHOXYFOS

한글명:CHLORETHOXYFOS

카스 번호54593-83-8

상품명:CHLORETHOXYFOS

CBNumberCB3493500

분자식C6H11Cl4O3PS

포뮬러 무게336

MOL 파일54593-83-8.mol

화학적 성질

끓는 점	bp0.05 torr 80°
밀도	d420 1.464
증기압	0.11 Pa (25 °C)
굴절률	nD25 1.4980
인화점	128℃
저장 조건	2-8°C
용해도	클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태	기름
수용성	2.1mg l^-1(25°C)
색상	무색
EPA	Chlorethoxyfos (54593-83-8)

위험 및 안전 성명

위험품 표기	T+,N
위험 카페고리 넘버	26/27/28-36-50/53
안전지침서	26-28-36/37-45-60-61
유엔번호(UN No.)	2783
위험 등급	6.1(a)
포장분류	I
HS 번호	29201900
유해 물질 데이터	54593-83-8(Hazardous Substances Data)
독성	LD50 in rats, mice (mg/kg): 1-10, 20-50 orally; in rabbits (mg/kg): 20-200 dermally (Watkinson)

그림문자(GHS)

CHLORETHOXYFOS 화학적 특성, 용도, 생산

화학적 성질
Chlorethoxyfos is a colorless liquid. Technical chlorethoxyfos is a light-to- dark brown liquid. Stable at room temperature for ＞18 months; stable at 55°C for 2 weeks. Chlorethoxyfos is characterized as having a “strong” odor.
용도
Chlorethoxyfos is a soil-applied organophosphorus insecticide used to control various soil insects (e.g. corn rootworms) in maize.
농업용
Insecticide: Chlorethoxyfos is a restricted use organophosphate insecticide registered for use in the U.S. on field corn, seed corn, sweet corn, and popcorn for the control of corn rootworms, wireworms, cutworms, seed corn maggots, white grubs, and symphylans. A U.S. EPA restricted Use Pesticide (RUP). Not listed for use in EU countries.
상품명
DPX-43898®; FORTRESS 2.5G; FORTRESS® 5G; SD 208304®
잠재적 노출
An organophosphate insecticide, chlorethoxyfos is a restricted use organophosphate insecticide registered for use in the United States on field corn, seed corn, sweet corn, and popcorn for the control of corn rootworms, wireworms, cutworms, seed corn maggots, white grubs, and symphylans. A United States Environmental Protection Agency Restricted Use Pesticide (RUP). Not currently listed for use in EU countries.
Carcinogenicity
According to an EPA summary, an 18 month study in which mice were given diets with chlorethoxyphos (doses not provided) was negative for carcinogenicity . A 2 year rat feeding (doses not provided) study showed a slight, nonsignificant increase in kidney tumors, and EPA concluded “the study was adequate for carcinogenicity testing” but that it was difficult to clearly interpret the data as showing either the presence or the absence of a carcinogenic effect .
신진 대사 경로
Chlorethoxyfos undergoes extensive degradation and metabolism in water, soil, plants and animals. Cleavage of the P-O-tetrachloroethyl bond is the major degradation reaction of chlorethoxyfos. Dechlorination and oxidation of the tetrachloroethyl moiety yielded chloral, dichloroacetic acid and trichloroacetic acid as major degradation products. The extensive metabolism of chlorethoxyfos and its degradation products yielded ¹⁴CO2 and amino acids (glycine, serine, etc.). Oxidative desulfuration to yield chlorethoxyfos-oxon or O-de-ethylation reactions were not observed.
운송 방법
UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
비 호환성
May react violently with antimony(V) pentafluoride. Incompatible with lead diacetate, magnesium, silver nitrate. In the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus.
폐기물 처리
Destruction by alkali hydrolysis or incineration. May also be mixed with flammable solvent and sprayed into an incinerator equipped with after burner and scrubber. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Afterburner

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