톨릴플루아니드

한글명:톨릴플루아니드

카스 번호731-27-1

상품명:TOLYLFLUANID

CBNumberCB3438572

분자식C10H13Cl2FN2O2S2

포뮬러 무게347.26

MOL 파일731-27-1.mol

동의어(한글)

톨리플루아나이드

톨릴플루아니드

1,1-디클로로-N-((디메틸아미노)술포닐)-1-플루오로-N-(4-메틸페닐)-메탄술펜아미드

화학적 성질

녹는점	96°C
끓는 점	93℃
밀도	1.5132 (rough estimate)
증기압	2 x 10^-5 Pa (20 °C)
굴절률	1.6000 (estimate)
저장 조건	-20°C
용해도	메탄올,DMSO에 용해됨
수용성	0.9mg l^-1(20°C)
산도 계수 (pKa)	-5.06±0.50(Predicted)
색상 색인 번호	45430
BRN	2949607
LogP	3.900
EPA	Tolylfluanid (731-27-1)

위험 및 안전 성명

위험품 표기	T,N,T+
위험 카페고리 넘버	23-36/37/38-43-48/20-50/53-50-48/23-26
안전지침서	24-26-37-38-45-60-61-63-36/37/39-28
유엔번호(UN No.)	2588
WGK 독일	3
RTECS 번호	WO6560000
위험 등급	6.1(b)
포장분류	III
유해 물질 데이터	731-27-1(Hazardous Substances Data)

그림문자(GHS)

톨릴플루아니드 화학적 특성, 용도, 생산

용도
Tolylfluanid is used to control a wide range of fungal diseases on apples, grapes, strawberries and other fruit and storage diseases on many crops.
정의
ChEBI: A member of the class of sulfamides that is dichlofluanid in which the hydrogen at the para position of the phenyl group is replaced by a methyl group. A fungicide first marketed in 1971 and used in the cultivation of fruit and vegetables, as ell as in wood preservatives, it is no longer approved for use in the European Union.
신진 대사 경로
Tolylfluanid contains an unstable dichlorofluoromethylthio (sulfenyl) moiety that has been shown to undergo rapid hydrolytic and metabolic degradation to dimethylaminosulfotoluidide (2). By analogy with captan, presumably the dichlorofluoromethylthio moiety can be transferred to the sulfur atoms of cellular thiols such as cysteine and glutathione. Thus, in the presence of thiols tolylfluanid is probably cleaved at the N-S bond to form thiophosgene or its monofluoro analogue (3) and other gaseous products such as hydrogen sulfide, hydrogen chloride and carbonyl sulfide. Thiophosgene or its monofluoro analogue is rapidly hydrolysed by water. The dichlorofluoromethylthio group and thiophosgene may be intermediates in the formation of addition products, for example addition to cysteine affords thiazolidine-2-thione-4-carboxylica cid (4). A thiazolidine derivative of glutathione may also be formed. The main metabolic reactions in all media were cleavage of the N-S bond to give dimethylaminosulfotoluidide (2) followed by hydroxylation of the phenyl ring and oxidation of the methyl substituent on the phenyl ring. Glucoside conjugates were detected in plants and the cysteine adduct, thiazolidine-2- thione-4-carboxylic acid (4), was formed in rats.

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