시아노겐 요오드화물

한글명:시아노겐 요오드화물

카스 번호506-78-5

상품명:CYANOGEN IODIDE

CBNumberCB3345368

분자식CIN

포뮬러 무게152.92

MOL 파일506-78-5.mol

동의어(한글)

사이아노겐아이오다이드

시아노겐요오드화물

화학적 성질

녹는점	146 °C
끓는 점	154.34°C (rough estimate)
밀도	1.840
저장 조건	Refrigerator (+4°C)
용해도	soluble in H2O, ethanol, ethyl ether
물리적 상태	결정성 분말
색상	베이지부터 연한 갈색 또는 연한 핑크까지
수용성	H2O, EtOH, eth [CRC10]에 용해됨
노출 한도	Because cyanogen iodide is a solid with very low vapor pressure, it does not present any inhalation hazard.
EPA	Cyanogen iodide (506-78-5)

위험 및 안전 성명

유엔번호(UN No.)

3290

위험 등급

6.1(a)

포장분류

HS 번호

28530090

유해 물질 데이터

506-78-5(Hazardous Substances Data)

NFPA 704:

	0
1		0

그림문자(GHS)

그림문자(GHS)
신호 어

Danger
유해·위험 문구

H301：삼키면 유독함

H311：피부와 접촉하면 유독함

H315：피부에 자극을 일으킴

H319：눈에 심한 자극을 일으킴

H331：흡입하면 유독함

H335：호흡 자극성을 일으킬 수 있음
예방조치문구

P261：분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.

P264：취급 후에는 손을 철저히 씻으시오.

P264：취급 후에는 손을 철저히 씻으시오.

P270：이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.

P271：옥외 또는 환기가 잘 되는 곳에서만 취급하시오.

P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

P301+P310：삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

P302+P352：피부에 묻으면 다량의 물로 씻으시오.

P304+P340：흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.

P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

P311：의료기관(의사)의 진찰을 받으시오.

P312：불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.

P321：(…) 처치를 하시오.

P322：특정 조치(라벨의 … 참조)

P330：입을 씻어내시오.

P332+P313：피부 자극이 생기면 의학적인 조치· 조언을 구하시오.

P361：즉시 오염된 의복을 모두 벗을 것

P362：오염된 의복을 벗고 세척 후에 재사용하기

P363：다시 사용전 오염된 의류는 세척하시오.

P403+P233：용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.

P405：밀봉하여 저장하시오.

P501：...에 내용물 / 용기를 폐기 하시오.

시아노겐 요오드화물 화학적 특성, 용도, 생산

화학적 성질
Iodine cyanide (cyanogen iodide) appears as light pink crystalline or brown-coloured powder and is soluble in water. It is stable but sensitive to light. It is incompatible with strong acids, strong bases, and strong oxidising agents. Cyanogen iodide decomposes on contact with acids, bases, and ammonia alcohols and on heating producing toxic gases including hydrogen cyanide. It reacts with carbon dioxide or slowly with water to produce hydrogen cyanide.
용도
Generally for destroying all lower forms of life. In taxidermy for preserving insects, butterflies, etc.
일반 설명
White needles with a very pungent odor. Used in taxidermists' preservatives and generally for destroying all lower forms of life. Toxic by inhalation or ingestion.
공기와 물의 반응
Water soluble.
반응 프로필
Phosphorus(molten) plus CYANOGEN IODIDE reacts with incandescence to produce phosphorus iodide, [NFPA 491M, 1991]. Benzene and cyanogen halides yield HCl as a byproduct (Hagedorn, F. H. Gelbke, and Federal Republic of Germany. 2002. Nitriles. In Ullman Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA.).
건강위험
Cyanogen bromide is a highly poisonous substance. Toxic routes are oral intake and skin absorption. Acute toxic symptoms on test animals were convulsion, paralysis, and respiratory failure. Ingestion of a 5-g amount could be fatal to humans.
LDLo value, oral (cats): 18 mg/kg
LDLo value, subcutaneous (dogs): 19 mg/kg
Cyanogen iodide is an irritant to skin.
화재위험
When heated to decomposition, CYANOGEN IODIDE emits very toxic fumes of nitrogen oxides, cyanide, and iodide. Avoid phosphorus.
Safety Profile
A poison by ingestion and subcutaneous routes. Violent reaction with P. See other cyanogen entries; CYANIDE and IOdiDES. When heated to decomposition it emits very toxic fumes of NOx, CN-, and I-
잠재적 노출
Reacts slowly with water releasing hydrogen cyanide. Incompatible with phosphorus (molten); reacts with incandescence to produce phosphorus iodide . Contact with alcohols, acids, ammonia, carbon dioxide or alkaline material and bases produces toxic gases including hydrogen cyanide. Incompatible with nitriles.
운송 방법
UN2928 Toxic solids, corrosive, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, 8-Corrosive material, Technical Name Required. UN3290 Toxic solid, corrosive, inorganic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poisonous materials, 8-Corrosive material. UN1588 Cyanides, inorganic, solid, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials
Purification Methods
This compound is POISONOUS, and the precautions for cyanogen bromide (above) apply here. The reagent (ca 5.9g) is dissolved in boiling CHCl3 (15mL), filtered through a plug of glass wool into a 25mL Erlenmeyer flask. Cool to room temperature for 15minutes, then place it in an ice-salt bath and cool to -10o. This cooling causes a small aqueous layer to separate as ice. The ice is filtered with the CNI, but melts on the filter and is also removed with the CHCl3 used as washing liquid. The CNI which is collected on a sintered glass funnel is washed 3x with CHCl3 (1.5mL at 0o) and freed from last traces of solvent by placing it on a watch glass and exposing it to the atmosphere in a good fume cupboard at room temperature for 1hour to give colourless needles (ca 4.5g), m 146-147o (sealed capillary totally immersed in the oil bath). The yield depends slightly on the rapidity of the operation; in this way loss by sublimation can be minimised. If desired, it can be sublimed under reduced pressure at temperatures at which CNI is only slowly decomposed into I2 and (CN)2. The vacuum will need to be renewed constantly due to the volatility of CNI. [Bak & Hillebert Org Synth Coll Vol IV 207 1963.]
비 호환성
Reacts slowly with water releasing hydrogen cyanide. Incompatible with phosphorus (molten); reacts with incandescence to produce phosphorus iodide . Contact with alcohols, acids, ammonia, carbon dioxide or alkaline material and bases produces toxic gases including hydrogen cyanide. Incompatible with nitriles.
폐기물 처리
A suitable method for destroying cyanogen iodide may consist of treatment with caustic soda, followed by adding sodium hypochlorite (laundry bleach) to oxidize the cyanide to nontoxic cyanate.

시아노겐 요오드화물 준비 용품 및 원자재

시아노겐 요오드화물 관련 검색

Send Inquriy