브로목시닐

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Warning

• 유해·위험 문구

  H302：삼키면 유해함

  H410：장기적 영향에 의해 수생생물에 매우 유독함

• 예방조치문구

  P273：환경으로 배출하지 마시오.

브로목시닐 MSDS

• Ametryn

브로목시닐 화학적 특성, 용도, 생산

• 화학적 성질

  Ametryn is a colorless powder

• 용도

  Ametryn is a methylthiotriazine based herbicide which inhibits photosynthesis and other enzymatic processes. Ametryn is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and b ananas.

• 정의

  ChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by an ethylamino and an isopropylamino group at positions 4 and 6 respectively.

• 생산 방법

  Ametryn is a colorless crystal synthesized by reacting atrazine with methyl mercaptan in the presence of an equivalent of NaOH or by reacting 2-mercapto-4-ethylamino-6-isopropylamino- 1,3,5-triazine with a methylating agent in the presence of NaOH. It is stable in slightly acidic or alkaline media, but is hydrolyzed to the inactive 6-hydroxy derivative in strong acidic or basic media.

• 일반 설명

  Crystals. Melting point 190-192°F (88-89°C). Used as a herbicide.

• 반응 프로필

  An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

• 위험도

  Toxic by ingestion.

• 건강위험

  Moderately toxic by ingestion; human toxic-ity data not available; a mild irritant to skinand eye.
  LD50 oral (rat): 508 mg/kg
  LD50 oral (mouse): 965 mg/kg
  LD50 skin (rabbit): >5000 mg/kg.

• 농업용

  Herbicide: Ametryn is a herbicide which inhibits photosynthesis and other enzymatic processes. It is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and bananas. Uses are being supported in the U.S. only for the following agricultural crops: field corn, popcorn, sugarcane, and pineapple (EPA, 2005). Used in premixes with atrazine, diuron, simazine, and terbutryn. Not approved for use in the EU.

• 상품명

  AMESIP®; AMERTREX®; AMETREX; AMETRON SC®; AMETRYNE TECHNICAL®; AMIGAN®; AMULEX; CRISATRINE®; CRISATRINA®; DORUPLANT®; EVIK®; G-34162®; GESAPAX®; HERBIPAK®; KRISMAT®; OXON PRIMATOL Z 80®; SANCOPAX®; TRINATOX-D®

• 잠재적 노출

  Ametryn, a triazine and an organosulfide, amine compound A potential danger to those involved in the manufacture, formulation and application of this selective herbicide.

• Carcinogenicity

  No carcinogenic response was observed at the highest dose tested in lifetime studies, 2000 ppm, for both rats and mice.

• 환경귀착

  Biological. Cook and Hütter (1982) reported that bacterial cultures were capable of degrading ametryne forming the corresponding hydroxy derivative (hydroxyametryne)
  Soil. Although no products were reported, the half-life in soil is 70–120 days (Worthing and Hance, 1991)
  Groundwater. According to the U.S. EPA (1986) ametryn has a high potential to leach to groundwater
  Chemical/Physical. Hydrolyzes to the 6-hydroxy analog, especially in the presence of
  Photolytic. The dye-sensitized photodecomposition of ametryn was studied in aqueous, aerated solutions (Rejto et al., 1983). When an aqueous ametryn solution was irradiated in sunlight for several hours, 2-(methylthio)-4-(isopropylamino)-6-amino-

• 운송 방법

  UN2763 Triazine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

• 비 호환성

  Triazines are incompatible with nitric acid. Amines are chemical bases, they neutralize acids to form salts plus water with an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides.

• 폐기물 처리

  In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

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