2-PHENYLPROPIONALDEHYDE

한글명:2-PHENYLPROPIONALDEHYDE

카스 번호93-53-8

상품명:2-PHENYLPROPIONALDEHYDE

CBNumberCB0778080

분자식C9H10O

포뮬러 무게134.18

MOL 파일93-53-8.mol

화학적 성질

녹는점	60°C
끓는 점	92-94 °C/12 mmHg (lit.)
밀도	1.002 g/mL at 25 °C (lit.)
증기압	40Pa at 20℃
굴절률	n20/D 1.517(lit.)
FEMA	2886 \| 2-PHENYLPROPIONALDEHYDE
인화점	169 °F
저장 조건	2-8°C
용해도	대부분의 고정 오일인 프로필렌 글리콜에 용해됩니다. 글리세린에 불용성.
물리적 상태	액체
색상	무색의
냄새	디프로필렌 글리콜 중 10.00%. 신선하고 날카로운 녹색 히아신스 잎 라일락
?? ??	녹색
수용성	10μg/L
감도	Air Sensitive
JECFA Number	1467
BRN	4291321
InChIKey	IQVAERDLDAZARL-UHFFFAOYSA-N
LogP	1.96
CAS 데이터베이스	93-53-8(CAS DataBase Reference)
EPA	Benzeneacetaldehyde, .alpha.-methyl- (93-53-8)

위험 및 안전 성명

위험품 표기

위험 카페고리 넘버

36/37/38

안전지침서

26-36/37/39

WGK 독일

RTECS 번호

CY1460000

F 고인화성물질

9-23

TSCA

Yes

HS 번호

29122990

NFPA 704:

	2
2		1

그림문자(GHS)

2-PHENYLPROPIONALDEHYDE 화학적 특성, 용도, 생산

화학적 성질
2-PHENYLPROPIONALDEHYDE identified in dried mushroom, is a colorless liquid with a green hyacinth odor. Hydratropaldehyde can be hydrogenated to hydratropic alcohol, which is also used to a limited extent by reaction of p-ethylbenzyl chloride and isobutyric aldehyde in the presence of catalysts. The product is used in perfumes for, for example, household products.
출처
Reported found in microbially fermented tea and some varieties of mushrooms.
용도
2-Phenylpropionaldehyde is a precursor in the synthesis of N,N,β-Trimethyl-phenethylamine Hydrochloride (T796625).
제조 방법
By alkaline condensation of acetophenone and ethyl chloroacetate; also by distillation of methylphenyl ethylene glycol in 91% yields (under atmospheric pressure).
생산 방법
The most important synthetic route to 2-phenylpropionaldehyde is the rhodiumcatalyzed hydroformylation of styrene. The catalyst [HCo(CO)4] is unsuitable in this process because it favors the hydrogenation of styrene. The use of chiral rhodium complexes leads to the formation of optically active aldehydes when prochiral olefins, such as styrene, are used. Asymmetric hydroformylation, however, has so far found only small industrial application because of insufficient purity of the enantiomers. Other synthetic methods are the gas-phase oxidation of a-methylstyrene on Cu, Bi–Mo– P–SiO2, or Pd salt catalysts, the rearrangement of epoxidized a-methylstyrene, and the dehydrogenation of 2-phenyl-1-propanol on Ag catalysts at reaction temperatures of ca. 600 ℃.
일반 설명
2-Phenylpropionaldehyde is used in perfumes for its green hyacinth odor.
상품명
Floralozone (IFF), Florazon (Symrise).
Safety Profile
: Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
Purification Methods
It may contain up to 15% of acetophenone. Purify it via the bisulfite addition compound [Lodge & Heathcock J Am Chem Soc 109 3353 1987] and see Chapter 2 for preparation and decomposition of bisulfite adducts. [Beilstein 7 IV 695.]

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