1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン化学構造式

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン

化学名:1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン

CAS番号.319-85-7

英語名:BETA-HCH

CBNumberCB3676013

MFC6H6Cl6

MW290.83

MOL File319-85-7.mol

别名

β-ヘキサクロロシクロヘキサン

β-リンダン

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン物理性質

融点	≥300 °C
沸点	373.64°C (rough estimate)
比重(密度)	1.9 g/cm³
蒸気圧	4.66 at 25 °C (Banerjee et al., 1990)
屈折率	1.630 (589.3 nm)
闪点	11 °C
貯蔵温度	APPROX 4°C
溶解性	エタノール、ベンゼン、クロロホルムに可溶 (Weast, 1986)
外見	個体
水溶解度	0.24mg/L(25℃)
BRN	1907338
Henry's Law Constant	0.53 at 5 °C, 0.91 at 10 °C, 2.17 at 20 °C, 5.23 at 30 °C, 8.68 at 35 °C:in 3% NaCl solution: 1.09 at 5 °C, 1.48 at 15 °C, 2.76 at 25 °C, 4.24 at 35 °C (dynamic headspace-GC, Sahsuvar et al., 2003
InChI	1S/C6H6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-6H/t1-,2-,3+,4+,5-,6-
InChIKey	JLYXXMFPNIAWKQ-CDRYSYESSA-N
SMILES	Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@H](Cl)[C@@H](Cl)[C@@H]1Cl
EPAの化学物質情報	.beta.-Hexachlorocyclohexane (319-85-7)

安全性情報

主な危険性	F,T,N,Xi
Rフレーズ	11-23/24/25-39/23/24/25-50/53-40-25-21-67-66-52/53-36
Sフレーズ	7-16-24-45-36/37-61-60-22-26
RIDADR	UN1230 3/PG 2
WGK Germany	3
RTECS 番号	GV4375000
TSCA	TSCA listed
国連危険物分類	6.1
容器等級	III
ストレージクラス	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 3 Oral Acute Tox. 4 Dermal Aquatic Acute 1 Aquatic Chronic 1 Carc. 2
有毒物質データの	319-85-7(Hazardous Substances Data)
毒性	Acute oral LD50 for rats 6,000 mg/kg (RTECS, 1985).
化審法	第1種特定化学物質 &_& 化審法施行令第7条 &_& 化審法施行令第8条
安衛法	57-2
毒劇物取締法	III

危険有害性情報のコード(GHS)

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0101	1mL	￥14200	β-BHC Standard	購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-023	1mL	￥9800	β-BHC Standard	購入
関東化学株式会社(KANTO) 49802-34	100mg	￥25000	β‐ＨＣＨ標準品	購入
富士フイルム和光純薬株式会社(wako) CRM33376	50MG	￥7600	β-HCH certified reference material, TraceCERT?, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland	購入
Sigma-Aldrich Japan 48494	50MG	￥10100	PESTANAL?, analytical standard	購入

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン化学特性,用途語,生産方法

化学的特性
BHC is a white-to-brownish crystalline solid with a musty, phosgene-like odor.
物理的性質
Although β-BHC is a solid at room temperature, the odor threshold concentration is 0.32 μg/kg (Sigworth, 1964).
使用
β-1,2,3,4,5,6-Hexachlorocyclohexane is an organochloride which is one of the isomers of hexachlorocyclohexane and is also an byproduct of insecticide Lindane (L465990).
定義
ChEBI: The beta-isomer of hexachlorocyclohexane.
一般的な説明
Colorless crystals. Corrosive to aluminum and many other metals.
空気と水の反応
Slightly soluble in water.
反応プロフィール
Halogenated aliphatic compounds, such as BETA-HCH, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Dehydrochlorination occurs in the presence of alkalis.
健康ハザード
ACUTE/CHRONIC HAZARDS: Highly toxic carcinogen. May cause irritation on contact. Hazardous decomposition products.
安全性プロファイル
Confirmed carcinogen with experimental neoplastigenic data. Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of Cl-, HCl, and phosgene. See also BENZENE HEXACHLORIDE and other benzenehexachloride entries.
職業ばく露
The major commercial usage of BHC is based upon its insecticidal properties. α-BCH is used as an Agricultural chemical, pesticide, pharmaceutical, and veterinary drug. The 7-isomer has the highest acute toxic ity, but the other isomers are not without activity. It is gen erally advantageous to purify the 7-isomer from the less active isomers. The γ-isomer acts on the nervous system of insects, principally at the level of the nerve ganglia. As a result, lindane has been used against insects in a wide range of applications including treatment of animals, buildings, humans for ectoparasites, clothes; water for mosquitoes; living plants; seeds and soils. Some applications have been abandoned due to excessive residues, e.g., stored food stuffs. By voluntary action, the principal domestic producer of technical grade BHC requested cancellation of its BHC registrations on September 1, 1976. As of July 21, 1978, all registrants of pesticide products containing BHC voluntar ily canceled their registrations or switched their former BHC products to lindane formulations.
環境運命予測
Soil. No biodegradation of β-BHC was observed under denitrifying and sulfate-reduc ing conditions in a contaminated soil collected from The Netherlands (Bachmann et al., 1988). In four successive 7-day incubation periods, β-BHC (5 and 10 mg/L) was recalci trant to degradation in a settled domestic wastewater inoculum (Tabak et al., 1981).
Chemical/Physical. Emits very toxic fumes of chlorides, hydrochloric acid and phos gene when heated to decomposition (Lewis, 1990). β-BHC will not hydrolyze to any reasonable extent (Kollig, 1993).
輸送方法
UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
不和合性
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on contact with powdered iron, aluminum, zinc, and on contact with strong bases producing trichlorobenzene.
廃棄物の処理
A process has been developed for the destructive pyrolysis of benzene hexachloride @ 400 500℃ with a catalyst mixture which contains 5 10% of either cupric chloride, ferric chloride; zinc chloride; or aluminum chloride on activated carbon.

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン上流と下流の製品情報

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン生産企業

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサンスペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

319-85-7, 1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサンキーワード

Send Inquriy

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン

危険有害性情報のコード(GHS)

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン 価格

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン 化学特性,用途語,生産方法

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン 上流と下流の製品情報

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン 生産企業

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン スペクトルデータ(1HNMR、13CNMR、IR1、IR2、MS)

319-85-7, 1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン キーワード

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン価格

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン化学特性,用途語,生産方法

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン上流と下流の製品情報

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサン生産企業

1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサンスペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

319-85-7, 1α,2β,3α,4β,5α,6β-ヘキサクロロシクロヘキサンキーワード