N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン

化学名:N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン

CAS番号.1582-09-8

英語名:Trifluralin

CBNumberCB2344612

MFC13H16F3N3O4

MW335.28

MOL File1582-09-8.mol

别名

2,6-ジニトロ-N,N-ジプロピル-4-トリフルオロメチルアニリン

α,α,α-トリフルオロ-2,6-ジニトロ-N,N-ジプロピル-p-トルイジン

アルファ,アルファ,アルファ-トリフルオロ-2,6-ジニトロ-N,N-ジプロピル-パラ-トルイジン

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン物理性質

融点	48.5°C
沸点	139°C
比重(密度)	1.294
蒸気圧	1.97 at 30 °C (effusion method, DePablo, 1976)
闪点	100 °C
貯蔵温度	APPROX 4°C
溶解性	DMSO : ≥ 100 mg/mL (298.26 mM);Water : < 0.1 mg/mL (insoluble)
酸解離定数(Pka)	-1.45±0.50(Predicted)
外見	結晶性固体
色	明るいオレンジ
水溶解度	<0.01 g/100 mL で 22.5 ºC
Merck	13,9757
BRN	1893555
Henry's Law Constant	10.19 and 14.89 in distilled water and 33.3‰ NaCl at 20 °C, respectively (wetted-wall column, Rice et al., 1997a)
LogP	5.340
CAS データベース	1582-09-8(CAS DataBase Reference)
IARC	3 (Vol. 53) 1991
NISTの化学物質情報	Trifluralin(1582-09-8)
EPAの化学物質情報	Trifluralin (1582-09-8)

安全性情報

主な危険性	Xi;N,N,Xi,Xn,F
Rフレーズ	36-43-50/53-20/21/22-11-40
Sフレーズ	2-24-37-60-61-36-26-16-46-36/37
RIDADR	UN 2588
WGK Germany	2
RTECS 番号	XU9275000
国連危険物分類	9
容器等級	III
HSコード	29214300
有毒物質データの	1582-09-8(Hazardous Substances Data)
毒性	LD50 orally in rats: 500 mg/kg (Goldenthal)
化審法	一般化学物質
PRTR法	第1種指定化学物質
環境リスク評価	トリフルラリン(1582-09-8)

危険有害性情報のコード(GHS)

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-197S	1mL	￥5300	トリフルラリン Standard	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-197N	10mg	￥5300	トリフルラリン	購入
関東化学株式会社(KANTO) 49826-06	250mg	￥19000	トリフルラリン標準品	購入
関東化学株式会社(KANTO) 40852-96	200mg	￥10000	トリフルラリン標準品 >99.0%(GC)	購入
Sigma-Aldrich Japan 32061	250mg	￥9100	トリフルラリン PESTANAL?, analytical standard	購入

MSDS Information

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン化学特性,用途語,生産方法

外観
黄色～黄赤色、結晶性粉末～粉末
溶解性
水に難溶。アセトン, キシレンに易溶。エタノールに可溶。水0.184(pH 5), 0.221(pH 7), 0.189(pH 9)(全てmg/l)。アセトン, アセトニトリル,トルエン, 酢酸エチル＞1,000, メタノール33～40, ヘキサン50～67(全てg/l 25℃)。ヘキサンに溶ける。
農薬用途
除草剤
使用上の注意
アルゴン封入
説明
Trifluralin is a dinitroaniline herbicide that is approved for preemergence use to control broadleaf weeds in a variety of crops and plants. First approved nearly 50 years ago, trifluralin is a common commercially available herbicide which is used extensively in the United States and other countries. In the early 2000s, trifluralin was banned in Europe following reports of persistence in soil and groundwater leading to concerns of increased risk for toxicity. In general, trifluralin is viewed as a safe herbicide when used according to the instructions. Minimal to no toxicity has been reported in humans following either oral, dermal, or inhalation exposure. There is some evidence that once trifluralin enters the soil and groundwater, it undergoes a complex and extensive series of metabolic steps and can exist as multiple intermediaries depending on the extent of the degradation. This has led to findings that trifluralin may have elevated toxicity in certain aquatic wildlife as particular species of fish and tadpoles have displayed biomarkers of trifluralin toxicity following exposure. Larger vertebrates such as canines have also demonstrated toxicological profiles suggesting an elevated toxicity compared to humans.
化学的特性
Trifluralin is an orange crystalline solid.
使用
Trifluralin is a herbicide, first approved in 1963, for control of annual grasses and broadleaf weeds on a variety of crops. Trifluralin is registered for nonfood uses including residential use. Trifluralin comes in a variety of formulations and is applied as a soil-incorporated treatment.
定義
ChEBI: A substituted aniline that is N,N-dipropylaniline substituted by a nitro groups at positions 2 and 6 and a trifluoromethyl group at position 4. It is an agrochemical used as a pre-emergence herbicide.
一般的な説明
Yellow-orange crystalline solid. Denser than water and not soluble in water. Hence sinks in water. Melting point 48.5-49°C. Used as a selective pre emergence herbicide.
反応プロフィール
Trifluralin is a trifluoromethyl dinitroaniline derivative. Dinitroaniline has a record of industrial explosions. Nothing has been reported implicating Trifluralin in any such accidents. This may be because of the trifluoromethyl substitution may mitigate the instability of the molecule. However, care should be taken in the extremes of heat, shock, and friction sources that may trigger an explosive release of energy.
健康ハザード
Dust may irritate eyes. No toxic symptoms have been observed during the manufacture and use of Trifluralin.
火災危険
Special Hazards of Combustion Products: Toxic and irritating hydrogen fluoride gas may be formed in fires.
农业用途
Herbicide: Trifluralin is a selective, pre-emergence herbicide used to control many annual grasses and broadleaf weeds in a large variety of tree fruit, nut, vegetable, and grain crops, including soybeans, sunflowers, cotton, and alfalfa. It is also used on rights-of-way, on set-aside land (i.e., arable land temporarily taken out of use). A general use pesticide (GUP). Not approved for use in EU countries . Registered for use in the U.S.
製品名
AGREFLAN®; AGRIFLAN® 24; ASHLADE TRIMARAN®; AUTUMN KITE®; BROADSTRIKE®; BUCKLE®; CALLIFORT®; CAMPBELL'S TRIFLURON®; CHANDOR®; COMMENCE®; CRISALIN®; DEVRINOL T®; DIGERMIN®; ELANCOLAN®; FLINT®; FLORA®; FLURENE SE®; FLUTRIX®; FREEDOM®; GORDON’S WEEDER®; HERBIFLURIN®; IPERSAN®; JANUS®; L-36352®; LILLY 36,352®; LINNET®; MARKSMAN®; MARKSMAN 2, TRIGARD®; M. T. F®; NITRAN®; OLITREF®; ONSLAUGHT®; PREMERLIN 600 CE®; SINFLOWAN®; SOLO®; SU SEGURO CARPIDOR®; TEAM®; TREFANOCIDE®; TREFICON®; TREFLAN®; TREFLANOCIDE®; TRIFARMON®; TRIFLURALINA® 600; TRIFLUREX®; TRIFUREX®; TRIGARD®; TRIKEPIN®; TRILIN®; TRILIN® 10G; TRIM®; TRIMARAN®; TRIPART TRIFLURALIN 48 EC; TRISTAR®; TRUST®; TURFLAN®; URANUS® (trifluralin + linuron)
安全性プロファイル
Moderately toxic by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Fand NOx. See also FLUORIDES.
職業ばく露
A potential danger to those involved in the manufacture, formulation and application of this selective, preemergence herbicide.
輸送方法
UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
不和合性
Trifluralin is a trifluoromethyl dinitroaniline derivative. Dinitroaniline has a record of industrial explosions. Nothing has been reported implicating trifluralin in any such accidents. This may be because of the trifluoromethyl substitution may mitigate the instability of the molecule. However, care should be taken in the extremes of heat, shock, and friction sources that may trigger an explosive release of energy. Fluorocarbons can react violently with barium, potassium, sodium.
廃棄物の処理
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Trifluralin does contain fluorine, and therefore incineration presents the increased hazard of HF in the off-gases. Prior to incineration, fluorine-containing compounds should be mixed with slaked lime plus vermiculite, sodium carbonate or sand-soda ash mixture (90-10).

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン上流と下流の製品情報

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン生産企業

1582-09-8, N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリンキーワード

Send Inquriy

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン

危険有害性情報のコード(GHS)

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン 価格

MSDS Information

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン 化学特性,用途語,生産方法

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン 上流と下流の製品情報

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン 生産企業

1582-09-8, N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン キーワード

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン価格

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン化学特性,用途語,生産方法

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン上流と下流の製品情報

N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリン生産企業

1582-09-8, N,N-ジプロピル-2,6-ジニトロ-4-(トリフルオロメチル)アニリンキーワード