1,3,5,7-テトラニトロオクタヒドロ-1,3,5,7-テトラゾシン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H225：引火性の高い液体および蒸気

  H319：強い眼刺激

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P337+P313：眼の刺激が続く場合：医師の診断/手当てを受けること。

  P403+P235：換気の良い場所で保管すること。涼しいところに 置くこと。

1,3,5,7-テトラニトロオクタヒドロ-1,3,5,7-テトラゾシン 価格

1,3,5,7-テトラニトロオクタヒドロ-1,3,5,7-テトラゾシン 化学特性,用途語,生産方法

• 解説

  シクロテトラメチレンテトラニトラミン,HMX，オクトーゲンとも呼ばれる。シクロトリメチレントリニトラミン(RDX)とよく似ており，無水酢酸法でRDXを製造する際にわずかに副生する。製造条件によってはHMXの収率を高めることができる。無色の結晶で，α,β,γ,δの4種の結晶形があるが，β型が安定で衝撃に対しても比較的鈍感なので，β‐HMXが高性能耐熱爆薬の主成分として用いられる。爆速は比重1.89のとき9110m/sで，実用爆薬のなかでは最高である。

• 用途

  火薬、爆薬

• 化学的特性

  HMX (high-melting explosive) is a completely N-nitrated, eight-membered heterocyclic ring compound analogous to RDX. HMX has a molecular weight of 296.16 and a melting point of 204°C. Virtually none of the toxicity information on HMX was published, but it was reviewed by the EPA.

• 使用

  HMX has uses similar to RDX, that is, as a base charge for detonators and as an ingredient of bursting-charge and plastic explosives by the military.

• 定義

  ChEBI: A tetrazocane that is 1,3,5,7-tetrazocane in which the hydrogen atom attached to each of the nitrogens is replaced by a nitro group.

• 一般的な説明

  A white crystalline solid. Melting point 281°C. Practically insoluble in water. Water slurry mitigates explosion hazard. Used in solid propellants and explosives. The primary hazard is the blast effect and not flying projectiles and fragments.

• 空気と水の反応

  Insoluble in water.

• 反応プロフィール

  HMX is a high explosive. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water. Presence of metal oxides increases thermal sensitivity. Wetting reduces sensitivity toward detonation.

• 健康ハザード

  Fire may produce irritating, corrosive and/or toxic gases.

• 火災危険

  MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.

• 安全性プロファイル

  A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279OC. When heated to decomposition it emits toxicfumes of NOx. See also EXPLOSIVES, HIGH.

• 職業ばく露

  A potential danger to those involved in the manufacture of this material and its handling in munitions and solid-propellant manufacture. It is also used as a rat poison; a powerful military explosive; a base charge for detonators; and in plastic explosives.

• 輸送方法

  UN0483 Cyclotrimethylenetrinitramine, desensi- tized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized, Hazard Class: 1D; Labels: 1D- Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or frag- ment hazard) when exposed to fire. UN0072 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not ,15% water by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or fragment hazard) when exposed to fire.

• 不和合性

  Heat, physical damage, shock, and deto- nators. Detonates on contact with mercury fulminate. Keep away from other explosives, combustibles, oxidizers (such as chlorates, nitrates, perchlorates, permanganates, perox- ides; bromine, chlorine, and fluorine); reducing agents; and aqueous alkaline solutions.

• 廃棄物の処理

  Pour over soda ash, neutralize and flush to sewer with water. Also HMX may be recov- ered from solid propellant waste.

2691-41-0, 1,3,5,7-テトラニトロオクタヒドロ-1,3,5,7-テトラゾシン キーワード