2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド

化学名:2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド

CAS番号.2540-82-1

英語名:FORMOTHION

CBNumberCB0757865

MFC6H12NO4PS2

MW257.27

MOL File2540-82-1.mol

别名

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド

ホルモチオン

アフリックス

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド物理性質

融点	25.5℃
沸点	317.8±52.0 °C(Predicted)
比重(密度)	1.361 g/cm³ (20 ºC)
蒸気圧	1.13 x 10^-4 Pa (20 °C)
屈折率	1.5541 (589.3 nm 20℃)
闪点	25 °C
貯蔵温度	2-8°C
酸解離定数(Pka)	-1.79±0.70(Predicted)
水溶解度	2600 mg l^-1 (24 °C)
外見	個体
BRN	5942199
CAS データベース	2540-82-1(CAS DataBase Reference)
EPAの化学物質情報	Formothion (2540-82-1)

安全性情報

主な危険性	Xn
Rフレーズ	21/22-36/38-20/21/22-10
Sフレーズ	36/37-36-26
RIDADR	3018
WGK Germany	3
国連危険物分類	6.1(b)
容器等級	III
有毒物質データの	2540-82-1(Hazardous Substances Data)
毒性	LD50 in rats, rabbits (mg/kg): 350, 410 orally (Liesche)

危険有害性情報のコード(GHS)

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-149S-CN	1mL	￥32000	ホルモチオン Standard	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-149N	10mg	￥32000	ホルモチオン	購入
関東化学株式会社(KANTO) 49801-92	100mg	￥26000	ホルモチオン標準品	購入
Sigma-Aldrich Japan 46424	250mg	￥22100	ホルモチオン溶液 ~80% in xylene, PESTANAL?, analytical standard	購入
林純薬工業株式会社 99057821	100mg	￥28500	ホルモチオン ---	購入

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド化学特性,用途語,生産方法

外観
無色～緑黄褐色, 澄明～わずかな微濁の液体
溶解性
水に難溶。殆どの有機溶媒に可溶。水2.6g/l(24℃)。アルコール, エーテル,ケトン, クロロホルム, ベンゼン, トルエン, キシレンと完全に混和する。ヘキサンにわずかに溶ける。エタノール及びアセトンに極めて溶けやすく、水に溶けにくい。
農薬用途
殺虫剤
使用上の注意
不活性ガス封入
説明
Formothion is a pale yellow liquid or crystalline mass, decomposes on distillation, mp 25–26 ?C, vp 0.113 mPa (20 ?C). It is poorly soluble in water (2.6 g/L at 24 ?C) and miscible with most organic solvents, except aliphatic hydrocarbons. Log Kow = 1.47. Formothion is hydrolyzed in aqueous media to dimethoate (activation) and dimethoate carboxylic acid (degradation): DT₅₀ (23 ?C) at pH 3–9 is less than 1 d.
化学的特性
Formothion is an odorless, yellowish viscous oil or crystalline mass.
使用
Formothion is used to control sucking pests and internally feeding larvae in a variety of crops.
一般的な説明
Viscous yellow oil or a crystalline mass. Used as an insecticide and acaricide on crops and ornamentals. Not presently produced commercially in the U.S.
空気と水の反応
hydrolyzed by water especially under alkaline conditions. [EPA, 1998].
反応プロフィール
Organophosphates, such as FORMOTHION, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
危険性
Cholinesterase inhibitor.
健康ハザード
FORMOTHION is one of the least toxic systemic organophosphates. FORMOTHION is a compound of low to moderate toxicity. It causes the depression of cholinesterase, leading to accumulation of acetylcholine in the nervous system, which is believed to be responsible for the symptoms.
火災危険
When heated to decomposition, FORMOTHION emits very toxic fumes of nitrogen oxides, phosphorus oxides and sulfur oxides. FORMOTHION is an organophosphorus insecticide. Some of these materials may burn but none of them ignite readily. Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Avoid alkaline pesticides; hydrolyzed by water especially under alkaline conditions.
农业用途
Insecticide, Acaricide: Formothion is a systemic and contact insecticide used to control spider mites, aphids, psyllids, mealy bugs, whiteflies, jassids, leaf miners, ermine moths, and fruit flies. It is used on tree fruits, vines, olives, hops, cereals, sugar cane, rice. Formothion is available as an emulsifiable concentrate and an ultra-low-volume spray. A U.S. EPA restricted Use Pesticide (RUP). Not approved for use in EU countries
製品名
AFLIX®; ANTHIO®; ANTIO®; CP 53926®; S 6900®; SAN 244 I®; SAN 6913 I®; SAN 71071®; SPENCER S-6900®; VEL 4284®
安全性プロファイル
Poison by ingestion, inhalation, sh contact, and intravenous routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx. See also ESTERS.
職業ばく露
Formothion is an insecticide and acar icide for use on crops and ornamentals. Formothion is not currently produced commercially in the U.S.
代謝経路
Formothion is broken down in aqueous solution to approximately equal amounts of dimethoate and dimethoate carboxylic acid, the first of which is an activation step and the latter a degradative one. All studies which have investigated the fate of formothion in biological systems have identified these two metabolites but there is evidence that their formation is purely base-catalysed and not enzyme-catalysed. In this respect, the amide group of formothion is much more labile than that of dimethoate since dimethoate carboxylic acid has only been reported in metabolic studies and is not formed by base-catalysed hydrolysis of dimethoate.
輸送方法
UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
不和合性
Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the pres ence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.
廃棄物の処理
In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド生産企業

2540-82-1, 2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミドキーワード

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2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド

危険有害性情報のコード(GHS)

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド 価格

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド 化学特性,用途語,生産方法

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド 生産企業

2540-82-1, 2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド キーワード

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド価格

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド化学特性,用途語,生産方法

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド生産企業

2540-82-1, 2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミドキーワード