2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H226：引火性の液体および蒸気

  H302：飲み込むと有害

  H304：飲み込んで気道に侵入すると生命に危険のおそ れ

  H315：皮膚刺激

  H319：強い眼刺激

  H335：呼吸器への刺激のおそれ

  H373：長期にわたる、または反復暴露により臓器の障 害のおそれ

  H412：長期的影響により水生生物に有害

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P310：飲み込んだ場合：直ちに医師に連絡すること。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P331：無理に吐かせないこと。

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド 価格

2-[(ジメトキシホスフィノチオイル)チオ]-N-メチル-N-ホルミルアセトアミド 化学特性,用途語,生産方法

• 外観

  無色～緑黄褐色, 澄明～わずかな微濁の液体

• 溶解性

  水に難溶。殆どの有機溶媒に可溶。水2.6g/l(24℃)。アルコール, エーテル,ケトン, クロロホルム, ベンゼン, トルエン, キシレンと完全に混和する。ヘキサンにわずかに溶ける。エタノール及びアセトンに極めて溶けやすく、水に溶けにくい。

• 農薬用途

  殺虫剤

• 使用上の注意

  不活性ガス封入

• 説明

  Formothion is a pale yellow liquid or crystalline mass, decomposes on distillation, mp 25–26 C, vp 0.113 mPa (20 C). It is poorly soluble in water (2.6 g/L at 24 C) and miscible with most organic solvents, except aliphatic hydrocarbons. Log Kow = 1.47. Formothion is hydrolyzed in aqueous media to dimethoate (activation) and dimethoate carboxylic acid (degradation): DT₅₀ (23 C) at pH 3–9 is less than 1 d.

• 化学的特性

  Formothion is an odorless, yellowish viscous oil or crystalline mass.

• 使用

  Formothion is used to control sucking pests and internally feeding larvae in a variety of crops.

• 一般的な説明

  Viscous yellow oil or a crystalline mass. Used as an insecticide and acaricide on crops and ornamentals. Not presently produced commercially in the U.S.

• 空気と水の反応

  hydrolyzed by water especially under alkaline conditions. [EPA, 1998].

• 反応プロフィール

  Organophosphates, such as FORMOTHION, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

• 危険性

  Cholinesterase inhibitor.

• 健康ハザード

  FORMOTHION is one of the least toxic systemic organophosphates. FORMOTHION is a compound of low to moderate toxicity. It causes the depression of cholinesterase, leading to accumulation of acetylcholine in the nervous system, which is believed to be responsible for the symptoms.

• 火災危険

  When heated to decomposition, FORMOTHION emits very toxic fumes of nitrogen oxides, phosphorus oxides and sulfur oxides. FORMOTHION is an organophosphorus insecticide. Some of these materials may burn but none of them ignite readily. Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Avoid alkaline pesticides; hydrolyzed by water especially under alkaline conditions.

• 农业用途

  Insecticide, Acaricide: Formothion is a systemic and contact insecticide used to control spider mites, aphids, psyllids, mealy bugs, whiteflies, jassids, leaf miners, ermine moths, and fruit flies. It is used on tree fruits, vines, olives, hops, cereals, sugar cane, rice. Formothion is available as an emulsifiable concentrate and an ultra-low-volume spray. A U.S. EPA restricted Use Pesticide (RUP). Not approved for use in EU countries

• 製品名

  AFLIX®; ANTHIO®; ANTIO®; CP 53926®; S 6900®; SAN 244 I®; SAN 6913 I®; SAN 71071®; SPENCER S-6900®; VEL 4284®

• 安全性プロファイル

  Poison by ingestion, inhalation, sh contact, and intravenous routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx. See also ESTERS.

• 職業ばく露

  Formothion is an insecticide and acar icide for use on crops and ornamentals. Formothion is not currently produced commercially in the U.S.

• 代謝経路

  Formothion is broken down in aqueous solution to approximately equal amounts of dimethoate and dimethoate carboxylic acid, the first of which is an activation step and the latter a degradative one. All studies which have investigated the fate of formothion in biological systems have identified these two metabolites but there is evidence that their formation is purely base-catalysed and not enzyme-catalysed. In this respect, the amide group of formothion is much more labile than that of dimethoate since dimethoate carboxylic acid has only been reported in metabolic studies and is not formed by base-catalysed hydrolysis of dimethoate.

• 輸送方法

  UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

• 不和合性

  Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the pres ence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

• 廃棄物の処理

  In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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