ChemicalBook > CAS DataBase List > Platinum dichloride

Platinum dichloride

CAS No.10025-65-7
Chemical Name:Platinum dichloride
CBNumber:CB9423657
Molecular Formula:Cl2Pt
Formula Weight:265.98
MOL File:10025-65-7.mol

Platinum dichloride Property

Melting point 581 °C (dec.)(lit.)
Density 6.05 g/mL at 25 °C
storage temp. Store below +30°C.
solubility insoluble in H2O, ethanol, ethyl ether; soluble in HCl
form Powder
Specific Gravity 6.05
color Green-brown
PH 5-6 (H2O)suspension
Water Solubility INSOLUBLE
Merck 14,7528
crystal system Monoclinic
Space group C2/m
Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3
1.3258 0.3194 0.6802 90 107.75 90 0.2743
CAS DataBase Reference 10025-65-7(CAS DataBase Reference)
FDA UNII 896SQ4TDHW
EPA Substance Registry System Platinium dichloride (10025-65-7)
UNSPSC Code 12352302
NACRES NA.23

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
1.3258	0.3194	0.6802	90	107.75	90	0.2743

Safety

Hazard Codes :C,Xi
Risk Statements :34-42/43-36/37/38-43
Safety Statements :22-26-36/37/39-45-27-24-37/39
RIDADR :UN 3260 8/PG 3
WGK Germany :2
RTECS :TP2275000
F :21
TSCA :Yes
HazardClass :8
HS Code :28439090
Hazardous Substances Data :10025-65-7(Hazardous Substances Data)
Toxicity :LD50 orally in Rabbit: 3423 mg/kg

NFPA 704:

	0
3		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H314-H317-H334
Precautionary statements P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Platinum dichloride Price More Price(20)

Brand: Sigma-Aldrich(India)
Product number: 8.24566
Product name : Platinum(II) chloride (73% Pt)
Purity: for synthesis
Packaging: 500MG
Price: ₹10720.01
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 520632
Product name : Platinum(II) chloride
Purity: ≥99.9% trace metals basis
Packaging: 1G
Price: ₹25596.6
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 520632
Product name : Platinum(II) chloride
Purity: ≥99.9% trace metals basis
Packaging: 5G
Price: ₹78488.1
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich
Product number: 206091
Product name : Platinum(II) chloride
Purity: 98%
Packaging: 250MG
Price: ₹8824.5
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 206091
Product name : Platinum(II) chloride
Purity: 98%
Packaging: 250MG
Price: ₹8824.5
Updated: 2022/06/14
Buy: Buy

Platinum dichloride Chemical Properties,Usage,Production

Chemical Properties Olive Green Crystals
Uses Platinum (II) chloride is a catalyst used for a variety of C-C bond, C-O bond, and C-N bond formation.
Uses Platinum chloride is a useful inorganic reagent which has been used in the preparation and characterization of Ru-Pt core-shell nanoparticles.
Definition ChEBI: Platinum dichloride is a platinum coordination entity consisting of platinum(II) bound to two chlorine atoms. It has a role as a reagent and a catalyst.
reaction suitability reagent type: catalyst
core: platinum
Safety Profile Moderately toxic by ingestion. A skin irritant. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. See also PLATINUM COMPOUNDS.
Purification Methods It is purified by heating at 450o in a stream of Cl2 for 2hours. Some sublimation occurs because the PtCl2 sublimes completely at 560o as red (almost black) needles. This sublimate can be combined to the bulk chloride, and while still at ca 450o it should be transferred to a container and cooled in a desiccator. A probable impurity is PtCl4. To test for this add a few drops of H2O (in which PtCl4 is soluble) to the salt, filter and add an equal volume of saturated aqueous NH4Cl to the filtrate. If no precipitate is formed within 1minute, then the product is pure. If a precipitate appears, then the whole material should be washed with small volumes of H2O until the soluble PtCl4 is removed. The purified PtCl2 is partly dried by suction and then dried in a vacuum desiccator over P2O5. It is insoluble in H2O but soluble in HCl to form chloroplatinic acid (H2PtCl4) by disproportionation. [Cohen Inorg Synth VI 209 1960.]