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Diisopropylchlorosilane

Diisopropylchlorosilane Structure
Diisopropylchlorosilane
  • CAS No.2227-29-4
  • Chemical Name:Diisopropylchlorosilane
  • CBNumber:CB9249415
  • Molecular Formula:C6H15ClSi
  • Formula Weight:150.72
  • MOL File:2227-29-4.mol
Diisopropylchlorosilane Property
  • Boiling point 58-60 °C50 mm Hg(lit.)
  • Density 0.883 g/mL at 25 °C(lit.)
  • refractive index n20/D 1.429(lit.)
  • Flash point 72 °F
  • storage temp. Inert atmosphere,Room Temperature
  • solubility generally sol organic solvents; reacts with alcohols, ammonia,and water.
  • form clear liquid
  • color Colorless to Almost colorless
  • Specific Gravity 0.883
  • Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
  • BRN 2231355
  • InChI InChI=1S/C6H15ClSi/c1-5(2)8(7)6(3)4/h5-6,8H,1-4H3
  • InChIKey CGXYLRTYLIHXEE-UHFFFAOYSA-N
  • SMILES [SiH](Cl)(C(C)C)C(C)C
  • CAS DataBase Reference 2227-29-4(CAS DataBase Reference)
  • FDA UNII DVG177547J
  • EPA Substance Registry System Silane, chlorobis(1-methylethyl)- (2227-29-4)
  • UNSPSC Code 12352001
  • NACRES NA.22
Safety
  • Hazard Codes  :C
  • Risk Statements  :10-34
  • Safety Statements  :26-36/37/39-45
  • RIDADR  :UN 2986 8/PG 2
  • WGK Germany  :3
  • F  :10-21
  • TSCA  :Yes
  • HazardClass  :3.1
  • PackingGroup  :II
  • HS Code  :29319090
  • NFPA 704:
    3
    3 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H226-H314
  • Precautionary statements P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Diisopropylchlorosilane Price More Price(6)
  • Brand: Sigma-Aldrich
  • Product number: 375896
  • Product name : Chlorodiisopropylsilane
  • Purity: 97%
  • Packaging: 5G
  • Price: ₹7425.95
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 375896
  • Product name : Chlorodiisopropylsilane
  • Purity: 97%
  • Packaging: 5G
  • Price: ₹7425.95
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 375896
  • Product name : Chlorodiisopropylsilane
  • Purity: 97%
  • Packaging: 25G
  • Price: ₹28740.38
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 375896
  • Product name : Chlorodiisopropylsilane
  • Purity: 97%
  • Packaging: 25G
  • Price: ₹28740.38
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: C1492
  • Product name : Chlorodiisopropylsilane
  • Purity: min. 95.0 %
  • Packaging: 5ML
  • Price: ₹7200
  • Updated: 2022/05/26
  • Buy: Buy

Diisopropylchlorosilane Chemical Properties,Usage,Production

  • Physical properties bp 150–153°C,bp 54–55°C/45 mmHg; d 0.872 gmL?1
  • Uses Intramolecular hydrosilylation is also possible within β-diisopropylsilyloxy esters (13), constituting an exceptionally mild method for reducing ester groups to the aldehyde oxidation level (eq 4).The derivatives (13) may be synthesized from β-hydroxy esters (12) as described above for the analogous ketones. Treatment with fluoride ions (but not Lewis acids) induces hydride transfer to give alkoxysiladioxanes (14) in excellent yields (≥95%). Although usually performed in dichloromethane, the hydrosilylation may also be accomplished with ethyl acetate as solvent, providing strong evidence for intramolecularity.Reactions of DIISOPROPYLCHLOROSILANE
  • Application Used in a silylation-reduction-allylation sequence of β-hydroxy esters to homoallylic-substituted 1,3-diols. Used in the silylation-hydrosilation-oxidation of allyl alcohols to 1,3-diols. Reaction carried out in diastereoselective manner. Reduces β-hydroxy ketones to anti-1,3 diols.
  • Preparation obtained by reaction of trichlorosilane with isopropylmagnesium chloride;the original yield of 45% may be raised to 70–80% by employing conc hydrochloric acid to quench the reaction.
  • Purification Methods Impurities can be readily detected by 1H NMR. Purify it by fractional distillation [Gilman & Clark J Am Chem Soc 69 1499 1947, Allen et al. J Chem Soc 3668 1957].
Diisopropylchlorosilane Preparation Products And Raw materials
Raw materials
Preparation Products
Diisopropylchlorosilane Suppliers
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Diisopropylchlorosilane Spectrum
2227-29-4, DiisopropylchlorosilaneRelated Search:
  • Synthetic Organic Chemistry
  • Silicon Compounds (for Synthesis)
  • Si-H Compounds
  • Si-Cl Compounds
  • Si (Classes of Silicon Compounds)
  • Reduction
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  • 化学试剂
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  • 保护和衍生
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  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Si (Classes of Silicon Compounds)
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  • Monochlorosilanes
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  • 2227-29-4
  • DKSI121
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  • Diisopropylsilyl chloride
  • CHLORODIISOPROPYLSILANE
  • C6H15ClSi DIISOPROPYLCHLOROSILANE 2227-29-4
  • chlorobis(propan-2-yl)silane
  • Chlorodiisopropylsilane &gt
  • chloro-di(propan-2-yl)silicon
  • chloro(2,3-dimethylbutan-2-yl)silicon
  • DIISOPROPYLCHLOROSILANE
  • Silane, chlorobis(1-methylethyl)-

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