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TROPONE
TROPONE
- CAS No.539-80-0
- Chemical Name:TROPONE
- CBNumber:CB8724528
- Molecular Formula:C7H6O
- Formula Weight:106.12
- MOL File:539-80-0.mol
TROPONE Property
- Melting point -7°C
- Boiling point 113 °C/15 mmHg (lit.)
- Density 1.094 g/mL at 25 °C (lit.)
- refractive index n
20/D 1.615(lit.) - Flash point >110°C
- storage temp. -20°C
- solubility sol ether, dioxane, acetone, benzene, toluene, xylene, MeCN, CCl4; miscible with water.
- form Liquid
- color very deep brown
- BRN 1902335
- FDA UNII CO48X7SUFH
- UNSPSC Code 12352100
- NACRES NA.22
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H302+H312+H332-H315-H319
- Precautionary statements P501-P261-P270-P271-P264-P280-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330-P302+P352+P312-P304+P340+P312
TROPONE Price
More Price(4)
- Brand: Sigma-Aldrich(India)
- Product number: 252832
- Product name : Tropone
- Purity: 97%
- Packaging: 1G
- Price: ₹3615.55
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 252832
- Product name : Tropone
- Purity: 97%
- Packaging: 5G
- Price: ₹13466.3
- Updated: 2022/06/14
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-L00473-06
- Product name : Tropone, 97%
- Purity:
- Packaging: 5g
- Price: ₹11298
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-L00473-03
- Product name : Tropone, 97%
- Purity:
- Packaging: 1g
- Price: ₹5287
- Updated: 2022/05/26
- Buy: Buy
TROPONE Chemical Properties,Usage,Production
-
Uses
Tropone has been used in synthesis of:
- bicyclic δ-lactones via heterocyclic carbine-catalyzed [8+3] annulation pathway
- 6,7-benzobicyclo [3.2.2] nona-3,6,8-trien-2-one via thermal addition to bezyne
- Application Tropone can be used to prepare the synthon of cycloheptadiene-1-one; it is used as the basis for the synthesis of cycloheptadiene compounds, fluorene compounds, polycyclic compounds, and natural products.
- Preparation 2,4,6-cycloheptatrien-1-one (1) is a functionalized conjugated carbocyclic compound with diversified reactivity. The most popular and simple method of preparation involves oxidation of 1,3,5- Cycloheptatriene with Selenium(IV) Oxide-KH2PO4. Several other procedures have also been developed, among which electrooxidation of cycloheptatrienes and α-pyrone ring expansion via high-pressure cycloaddition of cyclopropenone acetals can be considered general methods of synthesis of tropones.
-
Synthesis Reference(s)
Journal of the American Chemical Society, 78, p. 5442, 1956 DOI: 10.1021/ja01601a077
The Journal of Organic Chemistry, 29, p. 960, 1964
Organic Syntheses, Coll. Vol. 9, p. 396, 1998 - General Description Metal-catalyzed [6+3] cycloaddition of tropone with azomethine ylides has been reported.
TROPONE Preparation Products And Raw materials
Raw materials
Preparation Products
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539-80-0, TROPONERelated Search:
- TROPONE Tropolone GLORIOSINE Colchicine TROPOLONE TOSYLATE DEMECOLCINE Hinokitiol colchiceine 5-Dibenzosuberenone 5-Bromo-2-methoxy-tropone Cycloheptatriene 2-CHLORO-2,4,6-CYCLOHEPTATRIEN-1-ONE TRIMETHYLCOLCHICINIC ACID 3,7-dihydroxytropolone trimethylcolchicinic acid methyl ether COLCHICINE, [RING C, METHOXY-3H] 2-methoxy-5-(2',3',4'-trimethoxyphenyl)tropone COLCHICINE SALICYLATED
- 高端化学
- Organic Building Blocks
- Ketones
- Building Blocks
- C7 to C8
- Carbonyl Compounds
- 环庚-2,4,6-三烯-1-酮
- 【草(之上)+卓】酮
- 2,4,6-环庚三烯-1-酮
- 环庚三烯酮,97%
- 环庚三烯酮
- 539-80-0
- cyclohepta-2,4,6-trien-1-one
- cyclohepta-2,4,6-trienone
- 2,4,6-CYCLOHEPTATRIEN-1-ONE
- Cycloheptane-2,4,6-triene-1-one
- 2,4,6-CYCLOHEPTATRIEN-1-ONE 97%
- Tropone,97%
- LABOTEST-BB LT00233179
- 2,4,6-CYCLOHEPTATRIENONE
- Tropon
- Cycloheptatrienone
- 2,4,6-Cycloheptatriene-1-one
- 2,4,6-Cyclo-heptatriene-1-one
- TROPONE