Reaction
ChemicalBook > CAS DataBase List > (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

Reaction
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Structure
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • CAS No.136705-77-6
  • Chemical Name:(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • CBNumber:CB8311290
  • Molecular Formula:C31H48F3O3P2RhS
  • Formula Weight:722.62
  • MOL File:136705-77-6.mol
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Property
  • storage temp. Refrigerator (+4°C)
  • form crystal
  • color orange
  • Sensitive Air Sensitive
  • Exposure limits ACGIH: TWA 1 mg/m3
    NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
  • UNSPSC Code 12352005
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Price More Price(2)
  • Brand: Sigma-Aldrich(India)
  • Product number: 698393
  • Product name : 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • Purity: 
  • Packaging: 50MG
  • Price: ₹5783.1
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 698393
  • Product name : 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • Purity: 
  • Packaging: 250MG
  • Price: ₹22111.2
  • Updated: 2022/06/14
  • Buy: Buy

(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

  • Reaction
    1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
    2. Forms superior catalysts for asymmetric reductive aminations.
    3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
    4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
    5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
    6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
    7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
    8. Palladium catalyzed asymmetric phosphination.
    Reactions of 136705-77-6_1
    Reactions of 136705-77-6_2
    Reactions of 136705-77-6_3
    Reactions of 136705-77-6_4
    Reactions of 136705-77-6_5
  • Chemical Properties orange to orange-brown crystals
  • Uses DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

    Catalyst for:
    • Stereoselective synthesis of δ-amino acid derivatives via asymmetric hydrogenation of acetylaminopentenoic acid derivatives
    • Stereoselective synthesis of manzacidins A and C via stereoselective hydrogenation
    • Stereoselective synthesis of tetracyclic core of manzamine A via Rh-catalyzed asymmetric hydrogenation, diastereoselective Diels-Alder reaction, Eschenmoser-Tanabe fragmentation, Chang′s amide formation, and Hofmann rearrangement
    • Asymmetric preparation of chiral Cbz-aminodifluorobutyric acid Me ester and its analogs
    • Biphasic catalytic hydrogenations in ionic liquids with addition of water as a second solvent
    • Preparation of cyclobutane-containing amino acids via asymmetric hydrogenations of cyclobutyl enamides
    • Asymmetric preparation of both enantiomers of (dimethoxycoumaryl)alanine as suitable fluorescent peptide labels
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Spectrum
136705-77-6, (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATERelated Search:
  • organometallic complex
  • 高端化学
  • C22H36P2C8H12CF3O3SRh
  • C31H48F3O3P2RhS
  • (-)-1,2-双((2R,5R)-2,5-二乙基膦基)苯(1,5-环辛二烯)三氟甲磺酸铑(I)
  • 1,2-双[(2R,5R)-2,5-二乙基膦]苯(环辛二烯)三氟甲磺酸铑(I)
  • 1,2-双[(2R,5R)-2,5-二乙基磷杂环戊烷基]苯(1,5-环辛二烯)铑(I) 三氟甲磺酸盐
  • (-)-1,2-双((2R,5R)-2,5-二乙基膦基)苯(1,5-环辛二烯)三氟甲磺酸铑(I)[(R,R)-ET-DUPHOS-RH
  • (-)-1,2-双((2R,5R)-2,5-二乙基膦酰基)苯(1,5-环辛二烯)铑(I)三氟甲烷磺酸盐
  • (-)-1,2-双[(2R,5R)-2,5-二乙基膦]苯(1,5-环辛二烯)铑(I) 三氟甲基磺酸盐
  • (-)-1,2-BIS((2R,5R)-2,5-二乙基)苯(辛二烯)三氟甲烷磺酰铹
  • (-)-1,2-BIS((2R,5R)-2,5-二乙基)苯(辛二烯)三氟甲烷磺酰铑
  • 1,2-双[(2R,5R)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)
  • 136705-77-6
  • 1,2-Bis[(2<i>R</i>,5<i>R</i>)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • (-)-1,2-Bis((2R,5R)-2,5-diethyL
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • (-)-1,2-Bis[(2R,5R)-diethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,98%
  • 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate,98+%(R,R)-Et-DUPHOS-Rh
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate(r,r)-et-duphos-rh
  • Bisdiethylphospholanobenzenecyclooctadienerhodiumtrifluorometanesulfon
  • (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethansulfonate
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate (R,R)-Et-DUPHOS-Rh
  • (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • (-)-1,2-BIS(2R,5R)-2,5-(DIETHYLPHOSPHOLONO)BENZENE(CYCLOACTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • (-)-1,2-BIS-((2R,5R)DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE
  • (R,R)-ET-DUPHOS-RH
  • (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE,98+%(R,R)-ET-DUPHOS-RH
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfona
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh

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