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FMoc-α-Me-Lys(Boc)-OH

FMoc-α-Me-Lys(Boc)-OH Structure
FMoc-α-Me-Lys(Boc)-OH
  • CAS No.1202003-49-3
  • Chemical Name:FMoc-α-Me-Lys(Boc)-OH
  • CBNumber:CB82729321
  • Molecular Formula:C27H34N2O6
  • Formula Weight:482.57
  • MOL File:1202003-49-3.mol
FMoc-α-Me-Lys(Boc)-OH Property
  • Boiling point 687.9±55.0 °C(Predicted)
  • Density 1.196±0.06 g/cm3(Predicted)
  • storage temp. 2-8°C
  • pka 3.92±0.41(Predicted)
  • form powder
  • color white
  • InChIKey MYQXEVZHWDILHG-MHZLTWQESA-N
  • SMILES C(O)(=O)[C@](C)(CCCCNC(OC(C)(C)C)=O)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335-H336-H351-H373
  • Precautionary statements P261-P281-P305+P351+P338

FMoc-α-Me-Lys(Boc)-OH Chemical Properties,Usage,Production

  • Chemical Properties White to off-white powder.
  • Uses (S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoic acid is a reagent in the preparation/biological evaluation of a vapreotide analogs containing (S)?-?α-?methyl-?lysine.
  • Synthesis Benzyl (2R,3S)-(?)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate (4) was successively alkylated with methyl iodide and 1,4-diiodobutane using a base. In each alkylation step anti-alkylated product formed exclusively. The iodo group was displaced with azide, which served as a precursor for the side-chain amino function. Catalytic hydrogenation with concomitant cleavage of the chiral auxiliary afforded (L)-α-Me-Lys-OH (9) in a total of four steps in good yield. (L)-Fmoc-α-Me-Lys(Boc)-OH (16) was obtained from 9 via regioselective benzyloxycarbonylation. Alternately, (L)-Fmoc-α-Me-Lys(Boc)-OH (16) was obtained via Staudinger reduction of azide (8) in a total of six steps in good yield.
FMoc-α-Me-Lys(Boc)-OH Preparation Products And Raw materials
Raw materials
Preparation Products
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FMoc-α-Me-Lys(Boc)-OH Spectrum
1202003-49-3, FMoc-α-Me-Lys(Boc)-OHRelated Search:
  • α-Methyl Amino Acids
  • 化学试剂
  • 氨基酸衍生物-Lys衍生物
  • 其他生化试剂
  • N-甲基氨基酸
  • 非天然氨基酸
  • 1202003-41-3
  • (S)-2-(FMOC-氨基)-6-(BOC-氨基)-2-甲基己酸
  • (S)-N-ALPHA-FMOC-N-EPSILON-BOC-ALPHA-METHYLLYSINE;≥98%
  • (S)-2-((((9H-芴-9-基)甲氧基)羰基)氨基)-6-((叔丁氧羰基)氨基)-2-甲基己酸
  • FMOC-N'-BOC-Α-甲基-L-赖氨酸
  • (S)-NΑ-FMOC-NΩ-BOC-Α-METHYLLYSINE
  • (S)-NΑ-FMOC-NΩ-BOC-Α-甲基赖氨酸
  • (S)-NA-FMOC-NW-BOC-A-甲基赖氨酸
  • (S)-2-((((9H-芴-9-基)甲氧基)羰基)氨基)-6-((叔丁氧基羰基)氨基)-2-甲基己酸
  • 英文同义词:(S)-2-((((9H-FLUOREN-9-YL)METHOXY)CARBONYL)AMINO)-6-((TERT-BUTOXYCARBONYL)AMINO)-2-METHYLHEXANOIC ACID
  • (S)-N-Α-FMOC-N-BOC-Α-甲基-L-赖氨酸
  • FMOC-伪-ME-LYS(BOC)-OH
  • N-FMOC-N'-BOC-Α-甲基-L-赖氨酸
  • N6-[叔丁氧羰基]-N2-[芴甲氧羰基]-2-甲基-L-赖氨酸C
  • N6-[叔丁氧羰基]-N2-[芴甲氧羰基]-2-甲基-L-赖氨酸
  • 1202003-49-3
  • (S)-2-(Fmoc-amino)-6-(Boc-amino)-2-methylhexanoic Acid
  • (S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoic acid
  • N-α-(9-Fluorenylmethoxycarbonyl)-N-ε-(t-butoxycarbonyl)-α-methyl-L-lysine
  • FMoc-α-Me-Lys(Boc)-OH USP/EP/BP
  • Fmoc-α-Me-Lys(Boc)-OH
  • N6-Boc-N2-Fmoc-2-methyl-L-Lysine
  • L-Lysine, N6-[(1,1-dimethylethoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-2-methyl-
  • Fmoc-alpha-Me-Lys(Boc)-OH
  • (S)-Na-Fmoc-Nw-Boc-A-Methyllysine
  • Fmoc-α-methyl-L-Lysine(Boc)
  • Fmoc-a-Me-Lys(Boc)-OH
  • (S)-N-ALPHA-FMOC-N-EPSILON-BOC-ALPHA-METHYLLYSINE, >97%
  • N6-Boc-N2-Fmoc-alfa-Me--L-Lys-OH
  • (9H-Fluoren-9-yl)MethOxy]Carbonyl Alpha-Methyl-Lys(Boc)-OH
  • (2S)-6-{[(tert-butoxy)carbonyl]amino}-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylhexanoic acid
  • Fmoc-alpha-Me-L-Lys(Boc)-OH
  • (S)-Na-Fmoc-NW-Boc-α-Methyllysine
  • (S)-NΑ-FMOC-NΩ-BOC-Α-METHYLLYSINE
  • (S)-N-ALPHA-FMOC-N-EPSILON-BOC-ALPHA-METHYLLYSINE
  • N6-[(1,1-Dimethylethoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-2-methyl-L-lysine

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